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Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes

Description: We are making progress on our investigation of the mechanism of olefin exchange with Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8}. We are probing this system by kinetic study of the reaction of Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8} with butyl acrylate (BA) under various pressures of ethylene.
Date: May 1, 1992
Creator: Norton, J.R.
Partner: UNT Libraries Government Documents Department
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Corners of Texas

Description: This volume contains popular folklore of Texas, including information about folk music, folk arts and crafts, history of Texas, prominent Texas writers, and other miscellaneous folklore. The index begins on page 285.
Date: 1993
Creator: Abernethy, Francis Edward
Partner: UNT Press
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Role of Polycrystallinity in Cdte and Cuinse Sub 2 Photovoltaic Cells

Description: The polycrystalline nature of thin-film CdTe and CuInSe{sub 2} solar cells continues to be a major factor in several individual losses that limit overall cell efficiency. This report describes progress in the quantitative separation of these losses, including both measurement and analysis procedures. It also applies these techniques to several individual cells to help document the overall progress with CdTe and CuInSe{sub 2} cells. Notably, CdTe cells from Photon Energy have reduced window phot… more
Date: January 1, 1991
Creator: Sites, J.R. (Colorado State Univ., Fort Collins, CO (United States))
Partner: UNT Libraries Government Documents Department

Oral History Interview with George Riley, February 3, 1994

Description: Interview with George Riley concerning his experiences while employed by the Civilian Conservation Corps during the Great Depression. Riley worked at camps in Duncan, Arizona (Company 1814); Fredonia, Arizona (Company 1814); and Grand Junction, Colorado (Company 3892).
Access: Restricted to UNT Community Members. Login required if off-campus.
Date: February 3, 1994
Creator: Henley, Shelly & Riley, George V.
Partner: UNT Oral History Program
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Mitigation action plan for remedial action at the Uranium Mill Tailing Sites and Disposal Site, Rifle, Colorado

Description: The Estes Gulch disposal site is approximately 10 kilometers (6 miles) north of the town of Rifle, off State Highway 13 on Federal land administered by the Bureau of Land Management. The Department of Energy (DOE) will transport the residual radioactive materials (RRM) by truck to the Estes Gulch disposal site via State Highway 13 and place it in a partially below-grade disposal cell. The RRM will be covered by an earthen radon barrier, frost protection layers, and a rock erosion protection lay… more
Date: July 1992
Partner: UNT Libraries Government Documents Department
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Direct Methane Conversion to Methanol

Description: Objective is to demonstrate the effectiveness of a catalytic membrane reactor (ceramic membrane combined with catalyst) to selectively produce methanol by partial oxidation of methane. None of the membranes tested in a high pressure system could selectively remove methanol, until a cooling tube was inserted inside the membrane reactor to quench the product stream; this effectively increased methanol selectivity 2[times] during methane oxidation. For both conditions, combined selectivity for met… more
Date: December 3, 1992
Creator: Falconer, J. L. & Noble, R. D.
Partner: UNT Libraries Government Documents Department
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Colorado Economic Impact Study on the Uranium Mill Tailings Remedial Action Project in Colorado: Colorado State Fiscal Year 1993

Description: The Colorado economic impact study summarizes employment and economic benefits to the state from activities associated with the Uranium Mill Tailings Remedial Action (UMTRA) Project during Colorado state fiscal year (FY) 1993. To capture employment benefits, a questionnaire was distributed to subcontractor employees at the active UMTRA Project sites of Grand Junction, Rifle, and Gunnison, Colorado. An estimated 52 percent of the employees working on the UMTRA Project responded to this informati… more
Date: November 12, 1993
Partner: UNT Libraries Government Documents Department
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Grassland/Atmosphere Response to Changing Climate: Coupling Regional and Local Scales. Final Report

Description: The objectives of the study were: to evaluate the response of grassland ecosystems to atmospheric change at regional and site scales, and to develop multiscaled modeling systems to relate ecological and atmospheric models with different spatial and temporal resolutions. A menu-driven shell was developed to facilitate use of models at different temporal scales and to facilitate exchange information between models at different temporal scales. A detailed ecosystem model predicted that C{sub 3} te… more
Date: October 1, 1993
Creator: Coughenour, M. B.; Kittel, T. G. F.; Pielke, R. A. & Eastman, J.
Partner: UNT Libraries Government Documents Department
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Development of a gas-to-particle conversion model for use in three-dimensional global sulfur budget studies. Final report, 1 August 1991--30 June 1992

Description: A fully-parameterized model for the formation and growth of aerosols via gas-to-particle conversion has been developed and tested. A particularly significant contribution is a new method for the prediction of numbers of particles nucleated using information on the vapor source rate, relative humidity, and preexisting aerosol alone, thus eliminating the need to solve a system of coupled ODEs. Preliminary tests indicate substantial reduction in computational costs, but it is recommended that the … more
Date: August 1, 1993
Creator: Kreidenweis, S. M.
Partner: UNT Libraries Government Documents Department
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Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site. Final report: Revision 1

Description: Surface and subsurface soil cleanup protocols for the Gunnison, Colorado, processing site are summarized as follows: In accordance with EPA-promulgated land cleanup standards, in situ Ra-226 is to be cleaned up based on bulk concentrations not exceeding 5 and 15 pCi/g in 15-cm surface and subsurface depth increments, averaged over 100m{sup 2} grid blocks, where the parent Ra-226 concentrations are greater than, or in secular equilibrium with, the Th-230 parent. In locations where Th-230 has dif… more
Date: December 1993
Creator: Gonzales, D.
Partner: UNT Libraries Government Documents Department
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Finding of No Significant Impact, Proposed Remediation of the Maybell Uranium Mill Processing Site, Maybell, Colorado

Description: The U.S. Department of Energy (DOE) has prepared an environmental assessment (EA) (DOE/EA-0347) on the proposed surface remediation of the Maybell uranium mill processing site in Moffat County, Colorado. The mill site contains radioactively contaminated materials from processing uranium ore that would be stabilized in place at the existing tailings pile location. Based on the analysis in the EA, DOE has determined that the proposed action does not constitute a major federal action significantly… more
Date: December 31, 1995
Partner: UNT Libraries Government Documents Department
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Environmental Assessment of Remedial Action at the Maybell Uranium Mill Tailings Site Near Maybell, Colorado: Revision 2

Description: The purpose of this environmental assessment (EA) is to evaluate the environmental impacts resulting from remedial action at the Maybell uranium mill tailings site near Maybell, Colorado. A biological assessment and a floodplain/wetlands assessment are included as part of this EA. This report and attachments describe the proposed action, affected environment, and environmental impacts associated with the proposed remedial action, including impacts to threatened and endangered species listed or … more
Date: November 1994
Partner: UNT Libraries Government Documents Department
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Baseline Risk Assessment of Ground Water Contamination at the Uranium Mill Tailings Site Near Durango, Colorado

Description: This risk assessment evaluates the possibility of health and environmental risks from contaminated ground water at the uranium mill tailings site near Durango, Colorado. The former uranium processing site`s contaminated soil and material were removed and placed at a disposal site located in Body Canyon, Colorado, during 1986--1991 by the US Departments of Energy`s Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating the nature and extent of ground wa… more
Date: February 1995
Partner: UNT Libraries Government Documents Department
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Effects of Vegetation of Radon Transport Processes in Soil: The Origins and Pathways of {Sup 222}Rn Entering Into Basement Structures. Final Report, March 15, 1987--May 15, 1993

Description: The entry rate of {sup 22}Rn into a basement structure was measured continuously. These measurements demonstrated that radon entry did not vanish even when the structure was slightly pressurized. This persistent entry has been determined to be dominated by diffusion through the floor and walls and a combination of diffusion and convection through the floor-wall joint. The highest indoor radon concentrations occurred during calm periods when the pressure differentials between the inside and outs… more
Date: August 1, 1992
Creator: Borak, T. B.
Partner: UNT Libraries Government Documents Department
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Environmental Assessment of Remedial Action at the Slick Rock Uranium Mill Tailings Sites, Slick Rock, Colorado. Revision 1

Description: The Uranium Mill Tailings Radiation Control Act of 1978 (42 USC {section}7901 et seq.), hereafter referred to as the UMTRCA, authorized the US Department of Energy (DOE) to clean up two uranium mill tailings processing sites near Slick Rock, Colorado, in San Miquel County. Contaminated materials cover an estimated 63 acres of the Union Carbide (UC) processing site and 15 ac of the North Continent (NC) processing site. The sites are within 1 mile of each other and are adjacent to the Dolores Riv… more
Date: September 1, 1994
Partner: UNT Libraries Government Documents Department
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Role of polycrystallinity in CdTe and CuInSe{sub 2} photovoltaic cells. Annual subcontract report, 1 April 1991--31 March 1992

Description: The limiting role of polycrystallinity in thin-film solar calls has been reduced somewhat during the past year, and efficiencies of both CdTe and CuInSe{sub 2} cells are approaching 15%. Quantitative separation of loss mechanisms shows that individual losses, with the exception of forward recombination current, can be made comparable to their single crystal counterparts. One general manifestation of the extraneous trapping states in that the voltage of all polycrystalline thin-film cells drifts… more
Date: November 1, 1992
Creator: Sites, J. R.
Partner: UNT Libraries Government Documents Department
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Role of polycrystallinity in CdTe and CuInSe{sub 2} photovoltaic cells. Annual subcontract report, 1 April 1992--31 March 1993

Description: This report describes work to conduct several investigations of thin-film polycrystalline solar cells. (1) An analysis of high-efficiency solar cells fabricated at the University of South Florida showed significant reduction in forward recombination current, and the cells were stable over a 3-month test period. (2) Transient voltage effects were documented in a large number of polycrystalline cells and were attributed to long-lived trapping states sensitive to voltage changes near one-half open… more
Date: February 1, 1994
Creator: Sites, J. R.
Partner: UNT Libraries Government Documents Department
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Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Final report

Description: Assignment of the vibrational modes Of Os{sub 2}(CO){sub 8}(CHCH{sub 3}) and Os(CO){sub 4}(C{sub 2}H{sub 4)} has given fingerprint vibrational spectra for the following species when chemisorbed on metal catalyst surfaces: ethylidene and ethylene bound in a metallacyclopropane mode. The formation and fragmentation of diosmacyclobutanes have been shown to involve slippage of the outgoing olefin onto a single osmium, and associative exchange of the olefin from that site. The incorporation of vinyl… more
Date: April 25, 1994
Creator: Norton, J. R.
Partner: UNT Libraries Government Documents Department
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Remedial Action Plan and Site Design for Stabilization of the Inactive Uranium Processing Site at Naturita, Colorado. Remedial Action Selection Report, Appendix B of Attachment 2: Geology Report, Final

Description: The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section} 7901 et seq. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Envi… more
Date: March 1994
Partner: UNT Libraries Government Documents Department
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Diosmacycloalkanes as Models for the Formation of Hydrocarbons From Surface Methylenes. Progress Report, November 1, 1991--October 31, 1992

Description: We are making progress on our investigation of the mechanism of olefin exchange with Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8}. We are probing this system by kinetic study of the reaction of Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8} with butyl acrylate (BA) under various pressures of ethylene.
Date: May 1, 1992
Creator: Norton, J. R.
Partner: UNT Libraries Government Documents Department
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Remedial Action Plan and Site Design for Stabilization of the Inactive Uranium Mill Tailings Sites at Slick Rock, Colorado: Remedial Action Selection Report. Preliminary Final

Description: This proposed remedial action plan incorporates the results of detailed investigation of geologic, geomorphic, and seismic conditions at the proposed disposal site. The proposed remedial action will consist of relocating the uranium mill tailings, contaminated vicinity property materials, demolition debris, and windblown/waterborne materials to a permanent repository at the proposed Burro Canyon disposal cell. The proposed disposal site will be geomorphically stable. Seismic design parameters w… more
Date: March 1994
Partner: UNT Libraries Government Documents Department
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