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Preparation of Carrier Free Zr-Cb Tracer, Problem Assignment No. 263-X61C, Progress Report

Description: Technical report abstract. A rapid procedure for the preparation of very pure carrier-free Zr and Nb tracer involves the chloroform extraction of the cupferrides of Zr and Nb activities from process solutions. Zr and Nb form very stable chloroform soluble cupferrides in acid solutions (CK-993) and are separated from other fission elements almost quantitatively to yield pure mixture of Zr and Nb activity. A minimum of operations is required and the method is easily adaptable to remote control.
Date: August 28, 1944
Creator: Marinsky, Jacob A. (Jacob Akiba), 1918-2005 & Ballou, Nathan Elmer, 1919-
Item Type: Refine your search to only Report
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The Preparation of High-Purity Beryllium Oxide

Description: Abstract. A method for the preparation of beryllium oxide of high purity is presented. Beryllium basic acetate (BeO-3Be(C2H3O2)2) is prepared from the metal or a convenient salt, a chloroform solution of this material extracted with redistilled water, the dried basic acetate distilled in a quartz apparatus, and this purified material converted to the oxide by fuming down with sulfuric acid and igniting at 1000 degrees C. Impurities detectable spectrographically were reduced to a very low leve… more
Date: May 27, 1946
Creator: Tomkins, F. S.; Cressman, G. W. & Tolmach, L. J.
Item Type: Refine your search to only Report
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Procedures for the Separation of Products Resulting From Bombardment of Heavy Elements

Description: Technical report that attempts to bring together the various chemical procedures which proved most useful in studying the results of cyclotron bombardment or small scale neutron bombardments of heavy element targets. The report is limited to the elements of the "actinide", or second rare earth series, starting with thorium and including the newly discovered elements of atomic number 95 and 96. Every attempt is made to include all details necessary so this report can serve as a practical labora… more
Date: September 23, 1946
Creator: Thompson, Roy
Item Type: Refine your search to only Report
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Properties of Uranyl Fluoride

Description: Abstract: Pure UO2F2 is made by reaction between anhydrous HF and pure UO3. Although it is difficult to prepare free of water, it is not very hygroscopic. Prolonged heating at 100-105 degrees releases 99.9% of the water in an aqueous solution; the rate of loss of water is very small after saturation is reached. X-ray diffraction data give a density of 6.2 for the solid. The density of a 1.004 M solution is 1.274; the density of a saturated solution (5.130 M) is 2.400. The densities of F-9 s… more
Date: September 11, 1944
Creator: Dean, G. R.
Item Type: Refine your search to only Report
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Pyrohydrolysis in the Analysis of Fluorides and Other Halides

Description: Abstract. Fluorides and other halides are hydrolyzed completely by passing a rapid stream of superheated steam over the sample near 1000 degrees C in a specially designed platinum reaction tube. The steam and hydrogen halide are condensed by cooling, and the resulting distillate titrated with standard sodium hydroxide solution. The fluorides and chlorides of the light metals, hitherto thought of as very difficult to hydrolyze, are mixed with U3O8, or other metallic oxides, which reacts with … more
Date: June 30, 1945
Creator: Cline, W. D.
Item Type: Refine your search to only Report
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Radiocarbon from Pile Graphite; Chemical Methods for its Concentration

Description: Abstract. Samples of pile graphite, irradiated in a test-hole at Hanford for 15 months, have been assayed for radioactive C14, yielding 0.38 ± 0.04 microcuries per gram. At this level of activity, the pile graphite contains very valuable amounts of C14. The relation between the above assay and the probable average assay of pile graphite is discussed, and it is concluded that the latter is almost certainly above 0.3 uc/ gram. Controlled oxidation of this graphite, either with oxygen at ~ 750°C,… more
Date: October 10, 1946
Creator: Arnold, James R. & Libby, Willard F.
Item Type: Refine your search to only Report
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The Rapid Determination of Nitric Acid and Thorium in Thorium Nitrate Solutions

Description: Abstract. The physico-chemical methods of determining nitric acid and thorium nitrate in solutions containing these two materials were investigated. Conductimetric titration with sodium hydroxide can be used to determine nitric acid accurately. the titration of thorium nitrate requires a separate standardization of the base however, since a basic salt is precipitated rather the normal hydroxide. The titration of thorium is reproductible however, so and empirical standardization can be used.… more
Date: November 27, 1945
Creator: Newton, A. S.; Powell, J. (James), 1932- & Figard, P
Item Type: Refine your search to only Report
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Recovery of D2O and UO2F2 by Distillation

Description: Technical report describing the purification and separation by distillation of UO2F2 from D2O. In the experiment which is discussed 2,129.6 lbs of UO2F2 were dissolved in 6,605 lbs of D2O. The average isotopic purity of the D2O decreased during the distillation from 99.77% to 99.73%. The dissolved impurities were less than those present originally in the heavy water.
Date: October 10, 1945
Creator: Fischer, R. & Wattenberg, Albert, 1917-
Item Type: Refine your search to only Report
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The Solubility of Helium in Tuballoy

Description: This technical report summarizes the work done in attempting to determine the solubility of helium in tuballoy. In general, the method used has been to allow the tuballoy to stand in contact with helium at one atmosphere presume at a fixed temperature for an extended period, then to pump off the excess helium to a low pressure in as short a time as possible (10-6 mm of Hg or less). The system was then closed off and the pressure increase was measured by a suitable gauge as a function of time.… more
Date: June 26, 1945
Creator: Seltz , H. & Young, C. W.
Item Type: Refine your search to only Report
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Studies on the Determination of Carbon by the Low Pressure Combustion Method

Description: Technical report: The apparatus for the low pressure combustion method of determining carbon in iron and steel has be redesigned to increase the speed of manipulation. It has been tested by running several thousand determinations and found to yield results in good agreement with Wooten's form of the apparatus. A detailed description of the equipment and its manipulation is given together with an account of experimental studies on the method. Results are also shown for the carbon content of c… more
Date: October 20, 1943
Creator: Murray, W M., Jr. & Ashley, S E. Q.
Item Type: Refine your search to only Report
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A Study of Thorium Peroxide Sulfate

Description: Abstract. Thorium peroxide was precipitated from thorium nitrate solutions containing varying amounts of sulfate ion and of hydrogen ion. The washed solids were analyzed both wet and dry. Analyses were made for thorium, peroxide oxygen, sulfate, nitrate, and water contents. X-ray powder photographs of the dried samples by W.H. Zachariasen showed the presence of only two phases. When precipitated from high sulfuric acid, the solid phase was isomorphous with Th(OO)SO4.3H20. More weakly acid … more
Date: October 1, 1945
Creator: Hamaker, John W.
Item Type: Refine your search to only Report
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Sweeping of Fission Gases from Solutions of U and Plutonium

Description: Technical report describing two experiments performed to compare the amounts of fission gases swept out of UNH solution with those amounts swept out of PU solution under idential condiditons. The charge wire technique was used. The essential date and the results are given in tables in the report.
Date: September 4, 1945
Creator: Adams, R. M. & Finkelstein, H.
Item Type: Refine your search to only Report
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Third Form of Bismuth Phosphate - X-ray Study

Description: Abstract. In addition to the hexagonal and monoclinic bismuth phosphate precipitates, whose structures are now known, a third crystalline phase has been found to appear in BiPO4 precipitates after (a) extremely long digestion in concentrated nitric acid; (b) oven drying at 800 degrees to 1000 degrees. Thought very small single crystals of the component have been isolated, nor crushed sample contained less than 30% of the beta-form. The cell size and symmetry of the crystal indicates that the… more
Date: September 7, 1944
Creator: Mooney, Rose Camille Le Dieu
Item Type: Refine your search to only Report
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Transference and Adsorption on Glass of Carrier Free Zirconium

Description: .Technical report describing the transference experiments. The carrying of zirconium and columbium by ferric hydroxide has a very marked dependence on pH. In the experiments it was noticed that the concentration of Zr activity in various solutions changed with time This indicated that the Zr was being adsorbed on the glass. The carrier free trace is adsorbed on glass. This effect must be considered in experiments with Zr tracer in glass apparatus.
Date: January 3, 1945
Creator: Dodgen, H. W. & Rollefson, G. F.
Item Type: Refine your search to only Report
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Uranium Hydride, a Review to January 1, 1944

Description: Abstract. A review of all work on uranium hydride published in the CC, CT, CN and CE reports to January 1, 1944, is presented. Some additional information not yet published has been included, so this report includes all data known from the above sources and at Ames to the above date. This report supersedes all previous report on uranium hydride coming out of the Ames laboratory.
Date: February 10, 1944
Creator: Newton, A. S.; Warf, J. C.; Johnson, O. & Nottorf, R.
Item Type: Refine your search to only Report
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Uranium Oxide Slurry Pumping Experiments

Description: Abstract: Experiments on colloid milling and pumping show that uranium trioxide, when carefully dehydrated, can be dispersed in water to form a relatively stable slurry, suitable for a homogeneous slurry pile. At temperatures considerably below those of anticipated pile operation particle size growth occurs attended by increase in settling rate and decrease in viscosity. Theses properties of the slurries may be strongly affected by impurities present as well as by special operating condition… more
Date: September 15, 1944
Creator: Brandt, R. & Dean, G. R.
Item Type: Refine your search to only Report
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The Wigner Effect in Graphite, Relationship Between Advantage Factor and Location of Samples in an Operating Pile

Description: Technical report. The extent of the Wigner effect in graphite at any point in a pile is sensitive to the local structural situation. It is greater near a slug. These control experiments give information on changes in graphite to be expected in selected places in the pile.
Date: October 20, 1944
Creator: Novick, A.; Neubert, T. J. & Burton, Milton, 1902-
Item Type: Refine your search to only Report
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