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open access

Analyzing Mass Spectrometry Imaging Data of 13C-Labeled Phospholipids in Camelina sativa and Thlaspi arvense (Pennycress) Embryos

Description: This article uses currently available software and techniques to describe a workflow to analyze ¹³C-labeled isotopologues of the membrane lipid and storage oil lipid intermediate—phosphatidylcholine (PC). Results demonstrated greater ¹³C-isotopic labeling in the cotyledons of developing embryos compared with the embryonic axis.
Date: March 4, 2021
Creator: Romsdahl, Trevor B.; Kambhampati, Shrikaar; Koley, Somnath; Yadav, Umesh P.; Alonso, Ana Paula; Allen, Doug K. et al.
open access

Chemical and Genetic Studies on the Formation of Pyrrolones During the Biosynthesis of Cytochalasans

Description: This article investigates the role of the highly conserved α,β-hydrolase enzymes PyiE and ORFZ during the biosynthesis of pyrichalasin H and the ACE1 metabolite, respectively, using gene knockout and complementation techniques. Taken together the results suggest that the α,β-hydrolase enzymes are essential for first ring cyclisation, but the precise nature of the intermediates remains to be determined.
Date: November 4, 2020
Creator: Zhang, Haili; Hantke, Verena; Bruhnke, Pia; Skellam, Elizabeth & Cox, Russell J.
open access

Combining semi-synthesis with plant and microbial biocatalysis: new frontiers in producing a chemical arsenal against cancer

Description: This article demonstrates the methods of semi-synthesis and biocatalysis that can be used as modules in succession and in different combinations to produce 6,8-dibromogenkwanin, a derivative of the anticancer natural product apigenin.
Date: June 4, 2018
Creator: Gary, Samuel; Adegboye, Janet; Popp, Brian; Cocuron, Jean-Christophe; Woodrum, Brooklyn & Kovinich, Nik
open access

Dissecting the transcriptional regulation of proanthocyanidin and anthocyanin biosynthesis in soybean (Glycine max)

Description: This article analyzes the transcriptional control of PA and anthocyanin biosynthesis in soybean. Results show that engineered PA biosynthesis in soybean exhibits qualitative and spatial differences from the better-studied model systems Arabidopsis thaliana and Medicago truncatula, and suggest targets for engineering PAs in soybean plants.
Date: February 4, 2021
Creator: Lu, Nan; Rao, Xiaolan; Jun, Ji Hyung & Dixon, R. A.
open access

Domestic Carnivore Interactions With Wildlife in the Cape Horn Biosphere Reserve, Chile: Husbandry and Perceptions of Impact From a Community Perspective

Description: This article contains results of surveys to pet owners and non-owners living in the Cape Horn Biosphere Reserve in order to understand husbandry and perceptions of impacts by unconfined, domestic carnivores.
Date: January 4, 2018
Creator: Schüttler, Elke; Saavedra-Aracena, Lorena & Jiménez, Jaime E.
open access

Effectiveness of a Single Prolonged Aerobic Exercise Session on Executive Function Task Performance in Physically Active Adults (21–70 Years of Age)

Description: Authors of the article sought to examine the effectiveness of an acute prolonged exercise session on post-exercise executive function in physically active adults and to assess if age or pre-exercise cognitive performance was predictive of the magnitude of change in executive task performance. Their results support the effectiveness of a single prolonged exercise bout to augment executive function in physically active adults, irrespective of age.
Date: February 4, 2023
Creator: Yates, Brandon A.; Armstrong, Lawrence E.; Lee, Elaine C.; Unverzagt, Frederick W.; Dadzie, Ekow Jr.; Williamson, Keith et al.
open access

Enhanced Corrosion Resistance and Surface Wettability of PVDF/ZnO and PVDF/TiO2 Composite Coatings: A Comparative Study

Description: Article describes how this study aims to enhance the practical performance of PVDF/ZnO and PVDF/TiO2 composite coatings known for their distinctive properties. The coatings, applied through spray coating with PVDF and ZnO or TiO2 nanoparticles on glass, steel, and aluminum substrates, underwent a comprehensive evaluation.
Date: October 4, 2023
Creator: Mohamed, Adel M. A.; Alateyah, Abdulrahman I.; Hasan, Hosam; Matli, Penchal Reddy; El-Sayed Seleman, Mohamed M.; Ahmed, Essam et al.
open access

Genome Mining of Plant NPFs Reveals Varying Conservation of Signature Motifs Associated With the Mechanism of Transport

Description: This article focuses on four structural features of nitrate peptide families/proton-coupled oligopeptide transporters/peptide transporters that have been shown by structural and functional studies to be essential to proton-coupled symport transport.
Date: December 4, 2018
Creator: Longo, Antonella; Miles, Nicholas W. & Dickstein, Rebecca
open access

Global Warming Potential Estimates for the C₁–C₃ Hydrochlorofluorocarbons (HCFCs) Included in the Kigali Amendment to the Montreal Protocol

Description: This article reports global warming potentials (GWPs) for all C₁-C₃ hydrochlorofluorocarbons (HCFCs) based on estimated atmospheric lifetimes and theoretical methods used to calculate infrared absorption spectra.
Date: May 4, 2018
Creator: Papanastasiou, Dimitrios K.; Beltrone, Allison; Marshall, Paul & Burkholder, James B. (James Bart), 1954-
open access

Homologues and homology and their related terms in phylogenetic systematics

Description: Article describes how, in the field of phylogenetic systematics, the terms homology and homologue and their relationship to cladistic terms such as character, character state, synapomorphy and symplesiomorphy, as well as their relationships to each other, have been and are still discussed frequently. A recent re-emergence of concepts of homology/homologue free of any reference to explanatory hypotheses prompted the authors to explore these concepts and their relationships to each other as well … more
Date: February 4, 2023
Creator: Göpel, Torben & Richter, Stefan
open access

Knock-on synthesis of tritopic calix[4]pyrrole host for enhanced anion interactions

Description: Author Manuscript version of an article reporting interactions of anionic guests with a tritopic peripherally functionalized conjugated calix[4]pyrrole host (1) prepared using a regioselective synthetic method.
Date: June 4, 2019
Creator: Webre, Whitney A.; D'Souza, Francis; Chahal, Mandeep K.; Labuta, Jan; Březina, Václav; Karr, Paul A. et al.
open access

Leaf Lipid Alterations in Response to Heat Stress of Arabidopsis thaliana

Description: Article measuring lipid levels with mass spectrometry to confirm the previously observed changes in Arabidopsis thaliana leaf lipids under three heat stress regimens. Additionally, in response to heat, increased oxidation of the fatty acyl chains of leaf galactolipids, sulfoquinovosyldiacylglycerols, and phosphatidylglycerols, and incorporation of oxidized acyl chains into acylated monogalactosyldiacylglycerols are shown. The authors also observed increased levels of digalactosylmonoacylglycero… more
Date: July 4, 2020
Creator: Shiva, Sunitha; Samarakoon, Thilani; Lowe, Kaleb A.; Roach, Charles; Vu, Hieu Sy; Colter, Madeline et al.
open access

Modulating Uranium Extraction Performance of Multivariate Covalent Organic Frameworks through Donor–Acceptor Linkers and Amidoxime Nanotraps

Description: Article presents a COF (covalent organic framework)-based adsorption-photocatalysis strategy for selective removal of uranyl from seawater in the absence of sacrificial reagents. This work shows that multivariate COF adsorption-photocatalysts can be rationally engineered to work efficiently and stably without sacrificial electron donors, thus opening the pathway for the economic and efficient extraction of uranium from the earth’s oceans.
Date: January 4, 2023
Creator: Hao, Mengjie; Xie, Yinghui; Liu, Xiaolu; Chen, Zhongshan; Yang, Hui; Waterhouse, Geoffrey I. N. et al.
open access

Mutations in Arabidopsis Fatty Acid Amide Hydrolase Reveal That Catalytic Activity Influences Growth but Not Sensitivity to Abscisic Acid or Pathogens

Description: Article showing that the enhanced growth and NAE tolerance of the AtFAAH overexpressing seedlings depends on the catalytic activity of AtFAAH, hypersensitivity to ABA and hypersusceptibility to nonhost pathogens are independent of its enzymatic activity. Findings suggest that the AtFAAH influences plant growth and interacts with ABA signaling and plant defense through distinctly different mechanisms.
Date: December 4, 2009
Creator: Kim, Sang-Chul; Kang, Li; Nagaraj, Satish; Blancaflor, Elison B.; Mysore, Kirankumar S. & Chapman, Kent D.
open access

New molecular architectures containing low-valent cluster centres with di- and trimetalated 2-vinylpyrazine ligands: synthesis and molecular structures of Ru5(CO)15(μ5-C4H2N2CH[double bond, length as m-dash]CH)(μ-H)2 and Ru8(CO)24(μ7-C4H2N2CH[double bond, length as m-dash]C)(μ-H)3

Description: Article details the reaction of Ru3(CO)12 with 2-vinylpyrazine, the aim of which was to synthesize clusters in which all of the donor atoms of the 2-vinylpyrazine ligand participate in bonding to the cluster core.
Date: July 4, 2019
Creator: Hossain, Md. Monir; Akter, Nahid; Ghosh, Shishir; Nesterov, Vladimir N.; Richmond, Michael G.; Hogarth, Graeme et al.
open access

Prioritizing riparian corridors for ecosystem restoration in urbanizing watersheds

Description: This article explores restoration, rather than protection, being the basis for developing a watershed level strategy for improving water quality in urbanizing watersheds.This study uses a geographical information system (GIS) approach that utilizes riparian characteristics extracted from 40-meter wide corridors centered on streams and rivers. The model was applied to 90 sub-watersheds in the watershed of an important drinking water reservoir in north central Texas, USA.
Date: February 4, 2020
Creator: Atkinson, Samuel F. & Lake, Matthew C.
open access

Re-evaluation of rate constants for the reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M)

Description: Article describes how rate constants for the dissociation/recombination reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M) are determined by a combination of quantum-chemical calculations and statistical unimolecular rate theory. Implications of the present re-evaluated rate constants for the modeling of high temperature ammonia oxidation kinetics are discussed, showing an only small influence of their precise values on the overall properties of the process.
Date: October 4, 2023
Creator: Cobos, Carlos J.; Glarborg, Peter; Marshall, Paul & Troe, Jürgen
open access

Self-Reporting Molecularly Imprinted Polymer for Label-Free Selective Electrochemical Sensing of p-synephrine†

Description: This article is taken from the Proceedings of the 5th International Symposium on Sensor Science (I3S 2017). Molecularly imprinted polymers (MIPs) can be used in applications in selective chemosensing.
Date: December 4, 2017
Creator: Lach, Patrycja; Cieplak, Maciej; Sharma, Piyush S.; Sosnowska, Marta; D'Souza, Francis & Kutner, Wlodzimierz
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