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Boron reclamation

Description: A process to recover high purity /sup 10/B enriched crystalline boron powder from a polymeric matrix was developed on a laboratory basis and ultimately scaled up to production capacity. The process is based on controlled pyrolysis of boron-filled scrap followed by an acid leach and dry sieving operation to return the powder to the required purity and particle size specifications. Typically, the recovery rate of the crystalline powder is in excess of 98.5 percent, and some of the remaining boron… more
Date: July 1, 1980
Creator: Smith, R. M.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Electrochemistry of Thiobacillus ferrooxidans reactions with pyrite

Description: The objective of this project is to provide the fundamental information on the mechanisms of bacterial leaching of pyrite. The knowledge of how bacterial leaching of pyrite functions is essential for design and development of a technology for coal cleaning with bacteria. The features of major electrochemical techniques will be examined to find out if any of them can provide a diagnostic information on the mechanisms of related reactions.
Date: January 1, 1992
Creator: Pesic, B.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Solar-thermal energy conversion and storage: cyclohexane dehydrogenation. Progress report, 30 September 1977-30 June 1978

Description: The objective of this project is to provide research support for the benzene/cyclohexane heat pipe development program at Sandia. The kinetics of the cyclohexane decomposition (energy collection) reaction over a commercially available naphtha reforming catalyst (RD-150, Englehard Industries) in the temperature range 400 to 800/sup 0/F and pressures of 1 to 40 atmospheres were measured. Significant amounts of side products such as toluene and butane were identified at temperatures above 550/sup … more
Date: July 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

A Novel Coal Feeder for Production of Low Sulfur Fuel

Description: During the past three months, the coal feeding system has been tested and currently undergoing evaluation at the University of Cincinnati. The system consists primarily of an auger feed tube which is used to both convey and provide desulfurization of a high sulfur coal feedstock. The coal is conveyed at temperatures ranging from 350 to 550{degrees}C and under normal atmospheric pressure. Under these mild processing conditions, the coal partially pyrolizes and emits sulfur in the form of hydroge… more
Date: January 1, 1990
Creator: Khang, S. J. & Keener, T. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Chemical Technology Division, Unit Operations Section Monthly Progress Report, February 1962

Description: In the operation of 6-in.-dia. foam-liquid columns, increase in either the liquid flow or foam flow caused increased channeling with increased HTU. Flooding values for the Immi mixer-settler were obtalned using the amine extraction final cycle Pu flowsheet. Two tests of the addltlon of uranyl nitrate to a thoria sol were made, one of which gave a good product and the other a product which disintegrated during calcination. Material balances for 22 waste calcination runs are summarized. (auth)
Date: August 23, 1962
Creator: Whatley, M. E.; Haas, P. A.; Horton, R. W.; Ryon, A. D.; Suddath, J. C. & Watson, C. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Sonic enhanced ash agglomeration and sulfur capture

Description: The major objective of the Phase 1 test program is to confirm the feasibility of the Manufacturing and Technology Conversion International, Inc. bimodal particle size approach to enhance particulate control by acoustic ash agglomeration. An ancillary objective of the Phase 1 effort is to demonstrate and confirm the feasibility of an acoustic field to enhance sulfur capture by increasing sorbent reactivity. Phase 1 tests are designed to cover the frequency range between 50 and 1400 Hz, establish… more
Date: January 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance … more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Exploring novel silicon-containing polymers---From preceramic polymers to conducting polymers with nonlinear optical properties

Description: Several new types of silicon-containing preceramic polymers, i.e., poly(diorganosilacetylene) and poly(diorganosilvinylene) have been synthesized with molecular weights from 10,000 to 120,000. These polymers could be thermally converted to SiC with a moderate to high char yields. Ready solubility and good processability made these types of polymers attractive in their applications to ceramics. The thermal polymerization of diethynyldiphenyl-silane, which was reported in 1968 to afford poly(diph… more
Date: October 7, 1991
Creator: Pang, Yi.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Energy Program annual report

Description: The national economy is particularly dependent on efficient electrical generation and transportation. Electrical demand continues to grow and will increasingly rely on coal and nuclear fuels. The nuclear power industry still has not found a solution to the problem of disposing of the waste produced by nuclear reactors. Although coal is in ample supply and the infrastructure is in place for its utilization, environmental problems and improved conversion processes remain technical challenges. In … more
Date: February 1, 1988
Creator: Borg, I.Y. (ed.)
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Coal Technology Program. Progress report for November 1977

Description: A block of Pittsburgh seam bituminous coal and a block of Wyodak subbituminous coal were pyrolyzed under reducing gas in support of in situ gasification. Information from previously completed block pyrolysis of bituminous coal under an argon atmosphere show that differences in evolved gas result from differences in heating rates. Compared to block pyrolysis at 0.3 C/sup 0//min, block pyrolysis at 3 C/sup 0//min produces less gas but gas with a higher heating value, yielding a higher overall pyr… more
Date: January 1, 1978
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Geothermal waste treatment biotechnology: Progress and advantages to the utilities

Description: Development of biotechnology for treatment of geothermal residual waste is aimed at the application of low-cost biochemical processes for the surface treatment and disposal of residual geothermal sludges. These processes, in addition to the lowering of disposal cost, are designed to be environmentally acceptable. Recent studies at Brookhaven National Laboratory (BNL) have shown that optimization of several process variables results in fast rates (<24h) of metal removal from residual sludges at … more
Date: March 1, 1992
Creator: Premuzic, E.T.; Lin, M.S. & Jin, J.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistan… more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

KINETIC EXPERIMENTS ON WATER BOILERS-"A" CORE REPORT-PART II. ANALYSIS OF RESULTS

Description: The status of the analytic portion of the KEWB program at the time of completion of the spherical core experiments is summarized. Three computer programs were developed for use in this analytic effort. The first reassembles and smooths three decades of reactor power data read separately from oscillogram records of reactor excursions. It then computes the logarithmic derivative of the power, energy release, fuel solution temperature, and temperature compensated reactivity. The second program uti… more
Date: February 1, 1962
Creator: Dunenfeld, M. comp.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Effects of energy related activities on the plankton of the Chesapeake Bay. Section 1. Progress report, 1 August 1976--30 September 1977

Description: Progress is reported on a comprehensive study of the ecology of the Chesapeake Bay estuary system. Emphasis is placed on seasonal variations of initial energy fixation by phytoplankton primary producers and subsequent energy transfer to herbivours and becterial heterotrophs. The impact of chemical and radioactive effluents from electric power plants on the ecology of Chesapeake Bay will be assessed. Data are included on the role of plankton metabolism in regenerating nutrients, nutrient exchang… more
Date: 1977~
Creator: Taft, Jay L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Terrestrial fate of coal-liquid constituents: behavior of alkyl anilines in soil

Description: The low molecular weight aromatic amines (anilines) are important water soluble constituents of coal liquids. The impact of anilines released to the terrestrial environment will largely depend on their mobility and persistence. Studies were conducted to investigate those processes governing the mobility and persistence of the alkylanilines, namely, soil sorption and chemical/microbial degradation. Soil sorption measurements were conducted on aniline and several methyl substituted anilines on A … more
Date: July 1, 1982
Creator: Felice, L. J.; Zachara, J. M. & Rogers, J. E.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Feasibility Studies of in-Situ Coal Gasification in the Warrior Coal Field. Quarterly Report

Description: Studies in support of in-situ gasification involved experiments in bench-scale combustors where three parameters were varied independently: initial fuel bed temperature, applied air flow and water vapor influx rate. Methods for measuring the thermal conductivity of solids at high temperatures were evaluated and measurements of the thermal conductivity and thermal diffusivity were made over a temperature range for several samples of coke. (LTN)
Date: January 1, 1980
Creator: Douglas, George W. & McKinley, Marvin D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Humic substance formation during wastewater infiltration

Description: Soil infiltration of wastewater effluents is a widely practiced method of treatment and disposal/reuse throughout the world. Renovation of the wastewater results from a wide variety of complex physicochemical and biological processes. One set of processes is speculated to involve the accumulation of organic matter by filtration and sorption followed by formation of humic substances. This humic substance formation can effect the performance of soil treatment systems by contributing to soil pore … more
Date: January 1, 1991
Creator: Siegrist, R.L. (Oak Ridge National Lab., TN (United States)); Hildmann-Smed, R.; Filip, Z.K. (Bundesgesundheitsamt (BGA), Langen (Germany). Inst. fuer Wasser-, Boden- und Lufthygiene) & Jenssen, P.D. (Norges Landbrukshoegskole, Aas (Norway). Centre for Soil and Environmental Research)
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

Cationically polymerizable monomers derived from renewable sources

Description: The objective of this project is to make use of products obtained from renewable plant sources as monomers for the direct production of polymers which can be used for a wide range of plastic applications. In this report is described progress in the synthesis and polymerization of cationically polymerizable monomers and oligomers derived from botanical oils, terpenes, natural rubber, and lignin. Nine different botanical oils were obtained from various sources, characterized and then epoxidized. … more
Date: October 1, 1991
Creator: Crivello, J. V.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Sodium Fluozirconate Precipitation Process for Zirconium Fuels. Part 1. Laboratory Development

Description: Precipitation, evaporation, and extraction feed preparation conditions are established for the removal of zirconium and fluoride from fuel dissolver product solutions by the addition of sodium formate. A sparingly soluble complex fluozirconate is formed. Ninety-five to 99% of the zirconium and fluoride is separated from the uranium losses of 0.1% or less. Chemical material balances, based on experimental data, were developed for two flowsheets. In one flowsheet, sufficient nitric acid is added … more
Date: May 15, 1962
Creator: Newby, B. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Role of groundwater oxidation potential and radiolysis on waste glass performance in crystalline repository environments

Description: Laboratory experiments have shown that groundwater conditions in a Stripa granite repository will be as reducing as those in a basalt repository. The final oxidation potential (Eh) at 70/sup 0/C for Stripa groundwater deaerated and equilibrated with crystalline granite was -0.45V. In contrast, the oxidation potential at 60/sup 0/C for Grande Ronde groundwater equilibrated with basalt was -0.40V. The reducing groundwater conditions were found to slightly decrease the time-dependent release of so… more
Date: January 1, 1985
Creator: Jantzen, Carol M. & Bibler, Ned E.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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