Evolution of the Surface Science of Catalysis from Single Crystals to Metal Nanoparticles under Pressure
Description:
Vacuum studies of metal single crystal surfaces using electron and molecular beam scattering revealed that the surface atoms relocate when the surface is clean (reconstruction) and when it is covered by adsorbates (adsorbate induced restructuring). It was also discovered that atomic steps and other low coordination surface sites are active for breaking chemical bonds (H-H, O=O, C-H, C=O and C-C) with high reaction probability. Investigations at high reactant pressures using sum frequency genera…
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Date:
March 6, 2008
Creator:
Somorjai, Gabor A. & Park, Jeong Y.
Partner:
UNT Libraries Government Documents Department