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Assessment of research and development (R and D) needs in ammonia safety and environmental control

Description: This report characterizes the ammonia industry operations, reviews current knowledge of ammonia release and subsequent impacts, summarizes the status of release prevention and control methods and identify research and development needs for safety and environmental control. Appendices include: accidental spills and human exposure; adiabatic mixing of liquid nitrogen and air; fire and explosion hazards; and environmental impact rating tables. (PSB)
Date: September 1, 1981
Creator: Brenchley, D.L.; Athey, G.F. & Bomelburg, H.J.
Partner: UNT Libraries Government Documents Department
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Severe accident core heatup transients in modular high temperature gas-cooled reactors without operating Reactor Cavity Cooling Systems

Description: The ultimate decay heat removal system for the current Modular High Temperature Gas-Cooled reactors is a completely passive natural convection air cooling loop. This paper considers an extremely remote accident scenario, where even this passive system fails, and heat rejection is only via a layer of thermal insulation to the reactor silo structure and the surrounding soil. The results show that even in this case the peak fuel temperatures remain well within safe limits. However, vessel and conc… more
Date: January 1, 1988
Creator: Kroeger, P. G.
Partner: UNT Libraries Government Documents Department
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Sonic enhanced ash agglomeration and sulfur capture

Description: The major objective of the Phase 1 test program is to confirm the feasibility of the Manufacturing and Technology Conversion International, Inc. bimodal particle size approach to enhance particulate control by acoustic ash agglomeration. An ancillary objective of the Phase 1 effort is to demonstrate and confirm the feasibility of an acoustic field to enhance sulfur capture by increasing sorbent reactivity. Phase 1 tests are designed to cover the frequency range between 50 and 1400 Hz, establish… more
Date: January 1, 1991
Partner: UNT Libraries Government Documents Department
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Synergistic capture mechanisms for alkali and sulfur species from combustion

Description: This report presents work done on a laboratory combustor in an attempt to identify mechanisms that govern the simultaneous capture of alkali and sulfur species using sorbent injection techniques. The mechanisms of capture fall into two broad categories i.e. Physical transport of alkali species (in vapor or condensed phase) to the sorbent surface and surface reaction between the alkali species and the sorbents. Water solubility, though not specific, has been used to get an indication of relative… more
Date: April 23, 1992
Creator: Peterson, T.W.; Shadman, F.; Wendt, J.O.L. & Mwabe, P.O.
Partner: UNT Libraries Government Documents Department
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Innovative approach to asbestos removal

Description: The most common asbestos materials used at the Savannah River site include: steam pipe insulation; powerhouse boiler insulation; wallboards; roofing materials; and cement products. Asbestos was also found in a number of other materials: aprons; gaskets; laboratory hot pads; and talcum powder used for gloves. Techniques for removal; personnel training; mechanical ventilation; and personnel isolation techniques are described for completing asbestos removal safely and without boiler downtime. (PSB) more
Date: January 1, 1984
Creator: Kahal, E J
Partner: UNT Libraries Government Documents Department
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Organic iodine removal from simulated dissolver off-gas streams using silver-exchanged mordenite

Description: The removal of methyl iodide by absorption onto silver mordenite was studied using a simulated off-gas from the fuel dissolution step of a nuclear fuel reprocessing plant. The methyl iodide absorption of silver mordenite was examined for the effects of NO/sub x/, humidity, iodine concentration, filter temperature, and filter pretreatment. The highest iodine loading achieved in these tests has been 34 mg CH/sub 3/I per g of substrate, approximately five times less than the elemental iodine loadi… more
Date: January 1, 1980
Creator: Jubin, R. T.
Partner: UNT Libraries Government Documents Department
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Hot cell studies of tritium removal from and dissolution of an irradiated thoria fuel

Description: Tritium removal and dissolution studies on an irradiated thoria-based fuel were conducted in the High Level Caves at the Savannah River Laboratory (SRL). The objectives of these studies were to define the effects of key process-related parameters on tritium evolution and subsequent dissolution. The test program at SRL determined the effects on tritium removal of particle size, heating temperature, oxidation, and agitation. ThO/sub 2//UO/sub 2/ (95%/5%) fuel from the Elk River Reactor, irradiate… more
Date: January 1, 1980
Creator: Pickett, J.B.
Partner: UNT Libraries Government Documents Department
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(Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio)

Description: An environmental investigation of ground water conditions has been undertaken at Wright-Patterson Air Force Base (WPAFB), Ohio to obtain data to assist in the evaluation of a potential removal action to prevent, to the extent practicable, migration of the contaminated ground water across Base boundaries. Field investigations were limited to the central section of the southwestern boundary of Area C and the Springfield Pike boundary of Area B. Further, the study was limited to a maximum depth of… more
Date: March 1, 1992
Partner: UNT Libraries Government Documents Department
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Removal of silica from Raft River geothermal water

Description: Lack of sufficient quantities of clean surface or near-surface water at Raft River for cooling purposes dictates that cooled geothermal fluid, effluent from the Raft River 5 MW(e) Pilot Power Plant, must also be used as condenser coolant. Prior testing revealed that a water-treatment system would be required to reduce silica and calcium concentrations of the cooling fluid. The water-treatment system specified was to use dolomitic lime for both pH adjustment and source of magnesium. The dolomiti… more
Date: June 1, 1980
Creator: Suciu, D. F. & Miller, R. L.
Partner: UNT Libraries Government Documents Department
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Passive safety and the advanced liquid metal reactors

Description: Advanced Liquid Metal Reactors being developed today in the USA are designed to make maximum use of passive safety features. Much of the LMR safety work at Argonne National Laboratory is concerned with demonstrating, both theoretically and experimentally, the effectiveness of the passive safety features. The characteristics that contribute to passive safety are discussed, with particular emphasis on decay heat removal systems, together with examples of Argonne's theoretical and experimental pro… more
Date: January 1, 1988
Creator: Hill, D.J.; Pedersen, D.R. & Marchaterre, J.F.
Partner: UNT Libraries Government Documents Department
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Hot gas desulfurization with oxides of zinc, iron, and vanadium

Description: The objective of this study is to develop an improved sorbent which can reduce H{sub 2}S levels up to 1 ppmv or less, which can stabilize zinc, and produce economically recoverable amounts of elemental sulfur during regeneration. For this purpose, the desulfurization performance of sorbents prepared by the addition of various amounts of V{sub 2}O{sub 5} to the zinc ferrite sorbent is investigated.
Date: January 1, 1992
Creator: Akyurtlu, J.F. & Akyurtlu, A.
Partner: UNT Libraries Government Documents Department
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Methanation in catalyst-sprayed tube wall reactors: a review

Description: The design and operation of catalyst-sprayed tube wall reactors for methanation are discussed. Reactor tubes were either coated on the inner surface or on the outer surface with a Raney nickel catalyst. A liquid coolant, which was opposite the catalyst-reactant gas-side, removed the heat of methanation. Catalyst performance, reactor operating conditions, spent catalyst analyses, and other results are presented for five PDU tests.
Date: September 1, 1980
Creator: Pennline, H. W.; Schehl, R. R.; Haynes, W. P. & Forney, A. J.
Partner: UNT Libraries Government Documents Department
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Hot gas cleanup using solid supported molten salt for integrated coal gasification/molten carbonate fuel cell power plants. Topical report, October 1982-December 1983

Description: Battelle, Pacific Northwest Laboratories is developing a solid supported molten salt (SSMS) hot gas cleanup process for integrated coal gasification/molten carbonate fuel cell (MCFC) power plants. Exploratory and demonstration experiments have been completed to select a salt composition and evaluate its potential for simultaneous hydrogen sulfide (H/sub 2/S) and hydrogen chloride (HCl) removal under the conditions projected for the MCFC plants. Results to date indicate that equilibrium capacity… more
Date: December 1, 1983
Creator: Lyke, S. E.; Sealock, L. J. Jr. & Roberts, G. L.
Partner: UNT Libraries Government Documents Department
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Dynamics of H sub 2 elimination from unsaturated hydrocarbons

Description: State-of-the-art laser and molecular beam techniques are used to study the dynamics of H{sub 2} elimination from 1,4-cyclohexadiene and ethylene. Information on the transition state configurations and the dynamics of the dissociation processes for these reactions is reported. 152 refs., 54 figs., 12 tabs.
Date: February 1, 1991
Creator: Cromwell, E.F.
Partner: UNT Libraries Government Documents Department
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A replaceable reflective film for solar concentrators

Description: The 3M Company manufactures a silvered acrylic film called ECP-305 that is regarded as the preferred reflective film for use on stretched-membrane heliostats. However, ECP-305 will degrade in time, due to both corrosion of the silver layer and delamination at the film's silver-to-acrylic interface, and will eventually need to be replaced. 3M uses a very aggressive adhesive on this film, and once it is laminated, replacement is very difficult. The purpose of this investigation was the developmen… more
Date: September 1, 1991
Partner: UNT Libraries Government Documents Department
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Performance of BNL-TSTA compound cryopump

Description: A compound cryopump using cryocondensation pumping for hydrogen isotopes and cryosorption pumping with coconut charcoal as adsorbent for helium was designed. This compound cryopump was subsequently built (by Janis Research, Stoneham, MA) and has been tested at Brookhaven, fulfilling the design requirements and are delivered to Tritium Systems Test Assembly (TSTA) Vacuum Facility at Los Alamos Scientific Laboratory (LASL) for on-line operations.
Date: January 1, 1980
Creator: Hseuh, H. C. & Worwetz, H. A.
Partner: UNT Libraries Government Documents Department
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Process for cleaning and removal of sulfur compounds from low Btu gases. Quarterly summary report, October--December 1977

Description: Problems which occurred in the startup of the remodelled process development unit are described. The extraction section of the plant performed well with sulfur recoveries exceeding the design value of 95%. (LTN)
Date: January 1, 1978
Creator: Moore, R. H.; Ham, D. G.; Mitchell, D. H.; Robertus, R. J. & Stegen, G. E.
Partner: UNT Libraries Government Documents Department
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Waste acid detoxification and reclamation: Phase 1, Project planning and concept development

Description: The objectives of this project are to develop processes for reducing the volume, quantity, and toxicity of metal-bearing waste acids. The primary incentives for implemeting these types of waste minimization processes are regulatory and economic in that they meet requirements in the Resource Conservation and Recovery Act and reduce the cost for treatment, storage, and disposal. Two precipitation processes and a distillation process are being developed to minimize waste from fuel fabrication oper… more
Date: February 1, 1988
Creator: Stewart, T. L. & Brouns, T. M.
Partner: UNT Libraries Government Documents Department
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Physical-Chemical Treatment of Tar Sand Processing Wastewater: [Final Report, Tasks 3-5]

Description: The dewatering properties of residuals generated by flotation/foam fractionation treatment of TS-1S wastewater were evaluated. The leachate potential was studied for both chemical coagulation and flotation/foam fractionation sludges. A preliminary economic analysis was made comparing selected sludge disposal options and summarizing previously reported economic analysis of the chemical treatment alternatives.
Date: November 1983
Creator: King, Paul H.
Partner: UNT Libraries Government Documents Department
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Arsenic Removal From Gaseous Streams

Description: Uranium feed materials, depending on the production process, have been found to contain arsenic (As) as a contaminant. Analyses show the As to be present as As pentafluoride (AsF{sub 5}) and/or hexafluoroarsenic acid (HAsF{sub 6}) and enter the enrichment cycle through contaminated hydrogen fluoride (HF). Problems related to corrosion of cylinder valves and plugging of feed lines and valves have been attributed to the As. Techniques to separate AsF{sub 5} from uranium hexafluoride (UF{sub 6}) u… more
Date: November 22, 1989
Creator: Russell, R. G. & Otey, M. G.
Partner: UNT Libraries Government Documents Department
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Sampling and characterization of sodium-water reaction products

Description: Sodium-water reaction products (SWRP) which had accumulated in the bottom of the reaction products tank (RPT) of the Large Leak Test Rig (LLTR) were sampled and characterized. Analysis showed that the SWRP consisted of NaOH, Na/sub 2/O, NaH, and Na, as expected, in varying proportions. The unreacted sodium in the samples examined ranged from 32 to 60% by weight. The SWRP reacts (dissolves) rapidly and completely with ethanol, and somewhat less rapidly and completely with Dowanol PM. A magnetic,… more
Date: October 13, 1977
Creator: Eichelberger, R.L.
Partner: UNT Libraries Government Documents Department
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RMDF leach-field decontamination. Final report

Description: The objective of the decontamination effort was to place the Radioactive Materials Disposal Facility (RMDF) leach field in a condition suitable for release for unrestricted use. Radioactively contaminated soil was excavated from the leach field to produce a condition of contamination as low as reasonably achievable (ALARA). The contaminated soil was boxed and shipped to an NRC-licensed burial site at Beatty, Nevada, and to the DOE burial site at Hanford, Washington. The soil excavation project … more
Date: September 15, 1982
Creator: Carroll, J W; Marzec, J M & Stelle, A M
Partner: UNT Libraries Government Documents Department
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