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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1979-December 31, 1979. [Pt/Rh, Ni/Rh, Ni/Pt/Rh, Ni, Ni/Ru, Ni/Pt, Ni/Co]

Description: Twelve steam reforming catalysts were evaluated using an autothermal reforming screening unit. Duplicate tests were run with two samples to determine test variability. The samples tested contained either base metals, precious metals, or combinations of base and precious metals. The test was capable of distinguishing among samples where gross variations in composition are the main factor; for example, catalysts containing 2% by weight precious metals are more active than catalysts containing 15%… more
Date: January 1, 1980
Creator: Yarrington, R M; Feins, I R; Hwang, H S & Mayer, C P
Partner: UNT Libraries Government Documents Department
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STAINLESS STEEL WASTES. III. LABORATORY STUDIES OF THE RATE OF REMOVAL OF STAINLESS STEEL IONS BY MERCURY CATHODE ELECTROLYSIS

Description: ABS> The removal rates of iron, nickel, and chromium from synthetic stainless steel waste solutions during electrolysis over a mercury cathode were studied. The loading capacity of the mercury for the stainless steel metals was estimated on the basis of laboratory experiments to be about two% by weight. The laboratory data indicated that, at an electrode potential of --1.80 voits vs S.C.E., 85 ampere-hours per liter of waste removed essentially all of the stainless steel ions from a sulfuric ac… more
Date: February 12, 1962
Creator: Anderson, D. R. & Rhodes, D. W.
Partner: UNT Libraries Government Documents Department
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Pacific Northwest Laboratory Report on Fusion Energy Research, April 1977 - June 1977

Description: The development of economic data for fusion power plants continued in a study estimating the potential impact of a shortage of materials important in fusion plant construction. In studies developing heat transfer and fluid flow design tools for fusion reactor blankets, preconceptual design studies were initiated to identify the potential design limits of water cooling in the first wall of Tokamak Next Step (TNS) concepts. In surface effects research clean gold samples were irradiated in the Uni… more
Date: July 1, 1977
Partner: UNT Libraries Government Documents Department
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Modeling studies on the precipitation of Kr after implantation into metals

Description: A rate-theory approach is applied to interpreting observations on the precipitation of Kr injected into Ni at temperatures between 25 and 560/degree/C. At temperatures of 400/degree/C or higher, the implanted Kr precipitates evolve into a bi-modal size distribution containing small solid precipitates and an additional population of larger, faceted bubbles. The calculations explore the dependence of the observed bi-modal distribution on the maximum size of the solid Kr precipitates and the effec… more
Date: February 1, 1988
Creator: Rest, J.
Partner: UNT Libraries Government Documents Department
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Catalytic steam gasification of bagasse for the production of methanol

Description: Pacific Northwest Laboratory (PNL) tested the catalytic gasification of bagasse for the production of methanol synthesis gas. The process uses steam, indirect heat, and a catalyst to produce synthesis gas in one step in fluidized bed gasifier. Both laboratory and process development scale (nominal 1 ton/day) gasifiers were used to test two different catalyst systems: (1) supported nickel catalysts and (2) alkali carbonates doped on the bagasse. This paper presents the results of laboratory and … more
Date: December 1, 1983
Creator: Baker, E.G. & Brown, M.D.
Partner: UNT Libraries Government Documents Department
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Radiation-induced segregation in HT-9 martensitic steel

Description: Miniature notched-bar specimens of normalized and tempered HT-9 were neutron irradiated to approx.13 dpa and broken at liquid nitrogen temperatures in a UHV chamber. Fracture surfaces were analyzed using scanning Auger electron spectroscopy. Following irradiation at 410/sup 0/C, the fracture surface contained a small number of large relatively smooth facets, which are thought to be prior austenite grain boundaries. Strong segregation of Ni, Cr, Si, and P was detected at these surfaces, the rema… more
Date: January 1, 1986
Creator: Clausing, R.E.; Heatherly, L.; Faulkner, R.G.; Rowcliffe, A.F. & Farrell, K.
Partner: UNT Libraries Government Documents Department
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Magnetic excitations in transition-metal ferromagnets. Recent progress and future prospects on neutron scattering experiments

Description: A review is given on current neutron scattering experiments at Brookhaven National Laboratory on transition-metal ferromagnets Ni, Fe, Pd/sub 2/MnSn and MnSi. The scattering intensity in constant-energy scans, observed above T/sub c/ in all of these materials, exhibited a clear peak at finite momentum transfers. Using a simple scattering function with double-Lorentzian shape, we demonstrate that this peak is a manifestation of simple diffusive spin fluctuations. Experimental results of several … more
Date: January 1, 1984
Creator: Uemura, Y.J.
Partner: UNT Libraries Government Documents Department
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Methanation in catalyst-sprayed tube wall reactors: a review

Description: The design and operation of catalyst-sprayed tube wall reactors for methanation are discussed. Reactor tubes were either coated on the inner surface or on the outer surface with a Raney nickel catalyst. A liquid coolant, which was opposite the catalyst-reactant gas-side, removed the heat of methanation. Catalyst performance, reactor operating conditions, spent catalyst analyses, and other results are presented for five PDU tests.
Date: September 1, 1980
Creator: Pennline, H. W.; Schehl, R. R.; Haynes, W. P. & Forney, A. J.
Partner: UNT Libraries Government Documents Department
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Electron energy loss spectroscopy of CH/sub 3/N/sub 2/CH/sub 3/ adsorbed on Ni(100), Ni(111), Cr(100), Cr(111)

Description: A study of the adsorption of CH/sub 3/N/sub 2/CH/sub 3/ on Ni(100), Ni(111), Cr(100), and Cr(111) using high resolution electron energy loss spectroscopy (EELS) is presented. Under approximately the same conditions of coverage, the vibrational spectra of CH/sub 3/N/sub 2/CH/sub 3/ on these four surfaces are quite distinct from one another, implying that the CH/sub 3/N/sub 2/CH/sub 3/-substrate interaction is very sensitive to the physical and electronic structure of each surface. In addition to… more
Date: July 1, 1985
Creator: Schulz, M.A.
Partner: UNT Libraries Government Documents Department
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Structure of NH/sub 3/ on Ni(111)

Description: In a recent study of the adsorption of NH/sub 3/ on NI(111) at T approx. 190 K using angle resolved UPS, it was concluded that NH/sub 3/ is molecularly adsorbed, and is bonded to the surface via the N atom with the H atoms oriented away from the surface. To study the bonding configuration using a direct and independent technique, we have examined NH/sub 3/ on Ni(111) using the electron stimulated desorption ion angular distribution (ESDIAD) method, coupled with temperature programmed desorption… more
Date: January 1, 1980
Creator: Madey, T. E.; Houston, J. E.; Seabury, C. W. & Rhodin, T. N.
Partner: UNT Libraries Government Documents Department
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Atomic structure of clusters through chemical reactions

Description: Techniques for the probing of isolated metal cluster structure through adsorbate binding patterns will be described. The saturation of clusters with reagents such as ammonia and nitrogen provides information on the number of preferred binding sites for these reagents. The dependence of this number on cluster size can suggest particular structural themes. The equilibrium reaction with water can be used to identify cluster sizes having especially enhanced binding for the water molecule. Again, th… more
Date: January 1, 1991
Creator: Riley, S.J.
Partner: UNT Libraries Government Documents Department
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Surface, interface and thin-film magnetism

Description: In the last quarter of the 20th century, with the information revolution and the ever growing need to acquire, store, and retrieve information, the science and technologies attached to magnetic recording have experienced an explosive growth. Central to those pursuits has been the materials science of magnetism as it applies to surfaces, interfaces, and thin films. This report discusses topics on thin-film magnetism such as: theory, physical effects, prospects, opportunities and future developme… more
Date: July 1, 1991
Creator: Falicov, L.M. (Lawrence Berkeley Lab., CA (United States) California Univ., Berkeley, CA (United States). Dept. of Physics)
Partner: UNT Libraries Government Documents Department
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Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

Description: This report describes progress on research during the eleventh quarter of this contract dealing with applications of coal pretreatment techniques in coal/oil co-processing and direct hydroliquefaction. The objectives of the project are to investigate various coal pretreatment techniques and to determine the effect of these pretreatment procedures on the reactivity of the coal. Reactivity enhancement will be evaluated under both direct hydroliquefaction and co-processing conditions. Coal convers… more
Date: 1991-06~
Creator: Baldwin, R. M.; Gaur, S. & Miller, R. L.
Partner: UNT Libraries Government Documents Department
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SORPTION OF URANIUM ON ZIRCONIUM OXIDE

Description: The sorption of the ions of uranium, copper, and nickel on hydrous zirconium oxide was investigated at temperatures from 25 to 250 deg C. The experiments were performed by equilibrating 5 ml of the test solution with 0.5 g of zirconium oxide in a titanium autoclave, which was heated by means of a rocking furnace. The sorption of uranium was affected by characteristics of the zirconium oxide, temperatare of equilibration, and concentrations of uranium and of free acid in the uranyl sulfate solut… more
Date: September 13, 1961
Creator: Goldstein, G.
Partner: UNT Libraries Government Documents Department
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Structural study of multilayered vanadium/nickel superlattices

Description: We have studied the microstructure of V/Ni metallic superlattice, using x-ray and neutron diffraction. We find a sharp and broad rocking curves around the first-order Bragg peak, and attribute them to a columnar structure which gives rise to two modulation structures; one the ordinary layered structure within the columns and the other the averaged modulation structure which produces the sharp rocking peak.
Date: July 1, 1985
Creator: Homma, H.; Lepetre, Y.; Murduck, J.M.; Schuller, I.K. & Majkrzak, C.F.
Partner: UNT Libraries Government Documents Department
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Spectra in the 60 )angstrom) to 345 )angstrom) wavelength region of elements injected into the PLT tokamak

Description: High resolution spectra of the elements Fe, Ni, Zn, Ge, Se, and Mo injected into the PLT tokamak were recorded by the 2-meter Schwob-Fraenkel soft X-ray multichannel spectrometer (SOXMOS). Spectra were recorded every 50 ms during the time before and after injection. The spectral lines of the injected element were very strong in the spectrum recorded immedately after injection, and the transition in the injected element were easily distinguished from the transitions in te intrinsic elements (C, … more
Date: March 1, 1988
Creator: Wouters, A.; Schwob, J.L.; Suckewer, S.; Seely, J.F.; Feldman, U. & Dave, J.H.
Partner: UNT Libraries Government Documents Department
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Chemical Processing Technology Quarterly Progress Report, January-March 1961

Description: Studies are reported on aqueous zirconium processing, dissolution of BeO- UO/sub 2/ ceramic fuel, the aqueous stainless steel process, the behavior of dibutyl phosphates, use of boron (boric acid) solution to assure critical safety, fluidized bed calcination, conversion of amorphous alumina to alpha alumina, the Demonstrational Waste Calcining Facility, removal of long-lived radioisotopes from waste solutions, separation of iron, nickel, and chromiun from stainless steel waste solutions, electr… more
Date: October 31, 1962
Creator: Bower, J. R.
Partner: UNT Libraries Government Documents Department
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Electroless nickel and ion-plated protective coatings for silvered glass mirrors

Description: A preliminary examination of two methods of protecting second surface silvered glass mirrors from environmental degradation is presented. One method employed silver mirrors overcoated with Al, Ni, 304 stainless steel, Cr, or an Al/Cu alloy prepared by ion-plating. The other method used conventional wet process silver mirrors protected with a thin electroless nickel coating. No attempt was made to optimize the coatings for either method. These experimental mirrors were compared with conventional… more
Date: April 1, 1982
Creator: Lind, M. A.; Chaudiere, D. A.; Dake, L. S. & Stewart, T. L.
Partner: UNT Libraries Government Documents Department
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