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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance … more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Hydrogen bonding in asphaltenes and coal. Progress report, March 1, 1977--August 31, 1977

Description: A calorimetric method is presented for the simultaneous evaluation of equilibrium constant, K, and molar enthalpy, ..delta..H/sup 0/, for 1 : 1 adduct formation of quinoline (Qu) with asphaltene (A), together with its acid/neutral (AA) fraction and its base (BA) fraction, isolated from a centrifuged liquid product (CLP) sample prepared from Kentucky hvAb coal at 27.6 MPa hydrogen pressure and 723K, with reactor charged with glass pellets. The same procedure was used to determine K and ..delta..… more
Date: August 1, 1977
Creator: Li, N. C. & Tewari, K. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistan… more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Asphalt Emulsion Radon Barrier Systems for Uranium Mill Tailings: An Overview of the Technology

Description: Pacific Northwest Laboratory (PNL), under contract to the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) office, has developed an asphalt emulsion cover system to reduce the release of radon from uranium mill tailings. The system has been field tested at Grand Junction, Colorado. Results from laboratory and field tests indicate that this system is effective in reducing radon release to near-background levels (<2.5 pCi m/sup -2/s/sup -1/) and has the propert… more
Date: March 1, 1984
Creator: Baker, E.G.; Hartley, J.N.; Freeman, H.D.; Gates, T.E.; Nelson, D.A. & Dunning, R.L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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The development of an integrated multistage fluid bed retorting process. [KENTORT II process--50-lb/hr]

Description: This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II). The KENTORT II process includes integral fluidized bed zone for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The work performed during this year involved projects that will contribute physical and chemical data for the final design of the 50-lb/hr retort. … more
Date: January 1, 1992
Creator: Carter, S.; Vego, A.; Taulbee, D. & Stehn, J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Heavy recycle solvent studies in two-stage coal liquefaction. Final technical report, September 1, 1982-December 30, 1983

Description: The objective of this program has been to study the chemistry of the components with high boiling points in a direct coal liquefaction recycle solvent and to identify those components which lead to higher overall yields and improved product stability in the initial coal dissolution step of direct coal liquefaction processes. The major conclusions are: -454 C recycle solvent is primarily aromatic hydrocarbons (73%) and contains almost no asphaltenes; +454 C recycle solvent is primarily asphalten… more
Date: January 10, 1984
Creator: Longanbach, J. R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Characterization of Oil and Gas Reservoir Heterogeneity

Description: The ultimate objective of this cooperative research project is to characterize Alaskan petroleum reservoirs in terms of their reserves, physical and chemical properties, geologic configuration in relation to lithofacies and structure, and development potential. The project has two tasks: Task 1 is a geological description of the reservoirs including petrophysical properties, i.e., porosity, permeability, permeability variation, formation depth, temperature, and net pay, facies changes and reser… more
Date: January 1, 1992
Creator: Sharma, G. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Recovery and reuse of asphalt roofing waste. Final report

Description: Burning of asphalt roofing waste as a fuel and incorporating asphalt roofing waste in bituminous paving were identified as the two outstanding resource recovery concepts out of ten studied. Four additional concepts might be worth considering under different market or technical circumstances. Another four concepts were rated as worth no further consideration at this time. This study of the recovery of the resource represented in asphalt roofing waste has identified the sources and quantities of … more
Date: February 2, 1984
Creator: Desai, S.; Graziano, G. & Shepherd, P.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Vaporization, dispersion, and radiant fluxes from LPG spills. Final technical report

Description: Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools and a Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted … more
Date: May 1, 1982
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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An sup 15 N NMR method for the characterization of organic sulfur in coal and coal products via iminosulfurane formation

Description: The indirect of organic sulfur by {sup 15}N NMR spectroscopy in the solid state is feasible by facile reactions providing the iminosulfurane structures. Unfortunately, nitrogen chemical shifts appear to be insufficiently sensitive to the nature of the sulfur substituent to be useful for structural studies. Further work is underway to determine the {sup 15}N chemical shifts of iminosulfuranes formed from dibenzothiophene, 4-4{prime}-dimethoxydiphenyl sulfide, and a sulfur-containing, methylated … more
Date: September 1, 1991
Creator: Franz, J. A.; Lamb, C. N. & Linehan, J. C.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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GC/MS characterization of condensable tars in the output stream of a stirred fixed-bed gasifier

Description: The output stream of the stirred fixed-bed gasifier at the Morgantown Energy Technology Center was sampled for total entrained material. A major portion of the entrained material, in addition to particles, is condensable tar that is subsequently removed from the process gas by wet scrubbing. Characterization of the entrained materials, specifically the tar, is important to establish contaminant levels and to evaluate performance of downstream cleanup units. Samples of tars were collected from t… more
Date: December 1, 1981
Creator: Lamey, S. C.; McCaskill, K. B. & Smith, R. R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Revegetation/rock cover for stabilization of inactive uranium mill tailings disposal sites

Description: Pacific Northwest Laboratory is developing design and performance guidelines for surface stabilization of inactive uranium mill tailings. In this work, vegetation and rock covers are being evaluated for maintaining long-term integrity of impoundment systems. Methods are being developed to estimate erosion rates associated with rock and/or vegetation covers, and to determine the effects of surface treatments on soil moisture. Interactions between surface treatments and barriers (radon and biolog… more
Date: July 1, 1982
Creator: Beedlow, P. A.; McShane, M. C. & Cadwell, L. L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Effects of process severity on physiochemical properties of preasphaltenes

Description: This paper describes the physical character and reactions of preasphaltenes made from a bituminous coal. The preasphaltenes were obtained by reacting Illinois No. 6 Burning Star coal in contact with SRC-II heavy distillate under hydrogen pressure in an Autoclave for various times (10 to 30 minutes) and temperatures (350 to 450/sup 0/C). The preasphaltenes were separated by using conventional Soxhlet extraction techniques. The primary question addressed was: Are preashaltenes produced under one … more
Date: January 1, 1982
Creator: Lynch, A. W. & Thomas, M. G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Chemistry and structure of coal-derived asphaltenes, Phase III. Quarterly progress report, July--September 1977

Description: The major benzene insoluble fraction, carboid, solvent-separated from Synthoil coal liquid, was found to be 90 wt.% soluble in pyridine. This fraction, which contains about 50% of the ash present in Synthoil coal liquid, could be 96% de-ashed by dissolution in pyridine. A hypothetical average structure for Synthoil asphaltene has been derived from analytical, VPO MW, x-ray, NMR and chemical functionality data. A self-association model has been developed for calculating molecular weights, and fr… more
Date: November 1, 1977
Creator: Yen, T. F.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Hanford protective barriers program: Status of asphalt barrier studies - FY 1989

Description: The Hanford Protective Barrier Program is evaluating alternate barriers to provide a means of meeting stringent water infiltration requirements. One type of alternate barrier being considered is an asphalt-based layer, 1.3 to 15 cm thick. Evaluations of these barriers were initiated in FY 1988, and, based on laboratory studies, two asphalt formulations were selected for further testing in small-tube lysimeters: a hot rubberized asphalt and an admixture of cationic asphalt emulsion and concrete … more
Date: November 1, 1989
Creator: Freeman, H.D. & Gee, G.W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Catalyst dispersion and activity under conditions of temperature-staged liquefaction

Description: The general objectives of this research are (1) to investigate the use of highly dispersed catalysts for the pretreatment of coal by mild hydrogenation, (2) to identify the active forms of the catalysts under reaction conditions and (3) to clarify the mechanisms of catalysis. The ultimate objective is to ascertain if mild catalytic hydrogenation resulting in very limited or no coal solubilization is an advantageous pretreatment for the transformation of coal into transportable fuels. The experi… more
Date: February 1, 1992
Creator: Davis, A.; Schobert, H.H.; Mitchell, G.D. & Artok, L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Characterization of Oil and Gas Reservoir Heterogeneity

Description: The ultimate objective of this cooperative research project is to characterize Alaskan petroleum reservoirs in terms of their reserves, physical and chemical properties, geologic configuration in relation to lithofacies and structure, and development potential. The project has two tasks: Task 1 is a geological description of the reservoirs including petrophysical properties, i.e., porosity, permeability, permeability variation, formation depth, temperature, and net pay, facies changes and reser… more
Date: January 1, 1991
Creator: Sharma, G. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Catalyst dispersion and activity under conditions of temperature- staged liquefaction

Description: The general objectives of this research are (1) to investigate the use of highly dispersed catalysts for the pretreatment of coal by mild hydrogenation, (2) to identify the active forms of the catalysts under reaction conditions and (3) to clarify the mechanisms of catalysis. The ultimate objective is to ascertain if mild catalytic hydrogenation resulting in very limited or no coal solubilization is an advantageous pretreatment for the transformation of coal into transportable fuels. The experi… more
Date: September 1, 1991
Creator: Davis, A.; Schobert, H.H.; Mitchell, G.D. & Artok, L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Characterization of Oil and Gas Reservoir Heterogeneity

Description: The objective of the cooperative research program is to characterize Alaskan reservoirs in terms of their reserves, physical and chemical properties, geologic configuration and structure, and the development potential. The tasks completed during this period include: (1) geologic reservoir description of Endicott Field; (2) petrographic characterization of core samples taken from selected stratigraphic horizons of the West Sak and Ugnu (Brookian) wells; (3) development of a polydispersed thermod… more
Date: January 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

State-of-the-art report on low-level radioactive waste treatment

Description: An attempt is made to identify the main sources of low-level radioactive wastes that are generated in the United States. To place the waste problem in perspective, rough estimates are given of the annual amounts of each generic type of waste that is generated. Most of the wet solid wastes arise from the cleanup of gaseous and liquid radioactive streams prior to discharge or recycle. The treatment of the process streams and the secondary wet solid wastes thus generated is described for each type… more
Date: September 1, 1980
Creator: Kibbey, A. H. & Godbee, H. W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Asphalt emulsion sealing of uranium mill tailings. 1979 annual report

Description: Uranium mill tailings are a source of low-level radiation and radioactive materials that may be released into the environment. Stabilization or disposal of these tailings in a safe and environmentally sound way is necessary to minimize radon exhalation and other radioactive releases. One of the most promising concepts for stabilizing uranium tailings is being investigated at the Pacific Northwest Laboratory: the use of asphalt emulsion to contain radon and other potentially hazardous materials … more
Date: June 1, 1980
Creator: Hartley, J. N.; Koehmstedt, P. L.; Esterl, D. J. & Freeman, H. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Characterization of Oil and Gas Reservoir Heterogeneity

Description: The ultimate objective of this cooperative research project is to characterize Alaskan petroleum reservoirs in terms of their reserves, physical and chemical properties, geologic configuration in relation to lithofacies and structure, and development potential. The project has two tasks: Task 1 is a geological description of the reservoirs including petrophysical properties, i.e., porosity, permeability, permeability variation, formation depth, temperature, and net pay, facies changes and reser… more
Date: January 1, 1991
Creator: Sharma, G. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor

Description: The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental co… more
Date: January 1, 1991
Creator: Longstaff, D. C.; Deo, M. D.; Hanson, F. V.; Oblad, A. G. & Tsai, C. H.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

A preliminary investigation of acid-catalyzed polymerization reactions of shale oil distillates

Description: Sinor (1989) reported that a major specialty market may exist for shale oil as an asphalt blending material. Shale oil can be converted to an asphalt blending material by acid catalyzed condensation and polymerization reactions of the many molecular species comprising the composition of shale oil. To simplify the investigation, crude shale oil was separated by distillation into three distillates of different hydrocarbon and heteroaromatic compositions. These distillates were then treated with t… more
Date: April 1, 1991
Creator: Netzel, D.A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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