Laser flash photolysis, EPR and raman studies of liquids at elevated pressures. Progress report, April 1, 1993--November 19, 1993
Description:
A laser flash photolysis kinetic study of a W(CO){sub 5} intermediate reacting with several different substituted 2,2{prime}-bipyridine ligands at pressures up to 150 MPa in liquid toluene has confirmed the considerable influence of steric hindrance on the mechanism of a thermal ring closure reaction. A similar laser flash photolysis kinetic study has been carried out with Mo(CO){sub 6} and several bidentate ligands resembling 2,2{prime}-bipyridine dissolved in supercritical carbon dioxide. A m…
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Date:
November 19, 1993
Creator:
Eyring, E. M.
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Partner:
UNT Libraries Government Documents Department