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Enthalpies and Heat Capacities of Solid and Molten Fluoride Mixtures

Description: The enthalpies and heat capacities of seventeen fluoride mixtures in the liquid state have been determined using Bunsen Ice Calorimeters and copper block calorimeters. The fluoride mixtures were composed of the fluorides of two or more of the following metals: lithium, sodium, potassium, beryllium, zirconium, and uranium. The enthalpies and heat capacities of most of these mixtures were studied in the solid state also. Estimates of the heat of fusion have been made. General empirical equations … more
Date: January 11, 1956
Creator: Powers, W. D. & Blalock, G. C.
Partner: UNT Libraries Government Documents Department
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The Influence of End Mirrors, High Density and Long Tube Length on Radial Diffusion

Description: Diffusion in an arc plasma across a magnetic field is investigated. The geometry is similar to that reported in ORNL-1890 but with the addition of magnetic mirrors on the ends of the arc chamber. It is shown that mirrors do not eliminate the "short circuit" effect. Comparison of the e-folding length, rₒ, of the radial ion density with and without mirrors, affords a direct measurement of ℓ/λ where ℓ is the arc length and λ the mean-free-path. In addition rₒ is independent of gas pressure with mi… more
Date: September 22, 1955
Creator: Simon, Albert
Partner: UNT Libraries Government Documents Department
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Analytical Chemistry Division Semiannual Progress Report For Period Ending October 20, 1955

Description: The development of ionic methods for the determination of corrosive products in the highly radioactive Homogeneous Reactor (HR) fuels has been of major interest in the work of the Ionic Analyses Laboratory. Methods for the spectrophotometric determination of aluminum and for the polarographic determination of iron in HR fuels have been developed. The polarographic determination of molybdenum in uranyl sulfate solutions was studied. A polarographic method for the determination of zinc was develo… more
Date: December 27, 1955
Creator: Kelley, M. T.; Susana, C. D. & Rooen, H. P.
Partner: UNT Libraries Government Documents Department
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Relative Biological Hazards of Radiations Expected in Homogeneous Reactors TBR and HPR

Description: An evaluation of the relative health hazards of radioisotopes produced in nuclear reactors is reported. The most important hazards were indicated to be I131, the Sr90 - Y90 chain, the Ce144 -Pr144 chain, Sr 89, the Ba140-La40 chain, Y91, the Zr95-Nb95 chain, Pr143, La140 , and Pa233. The most critical body organs affected by air-borne contamination are the thyroid gland, the bone marrow, the lungs, and the gastrointestinal tract. Where possible, continuous daily removal of gaseous and solid fis… more
Date: December 2, 1955
Creator: Arnold, E. D. & Gresky, A. T.
Partner: UNT Libraries Government Documents Department
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Determination of Trivalent Uranium with Methylene Blue

Description: A direct titrimetric method for the determination of trivalent uranium in uranium trifluoride and mixtures of fused fluoride salts was developed. The method is based on the stoichiometric oxidation of trivalent uranium to the tetravalent oxidation state with an acidic solution of methylene blue. The sample containing trivalent uranium is dissolved at room temperature in an excess of standard methylene blue solution in a carbon dioxide atmosphere; the excess oxidant is variation of the method is… more
Date: November 22, 1955
Creator: Ross, W. J.; Meyer, A. S.; White, J. C.; Kelley, N. T. & Susano, C. D.
Partner: UNT Libraries Government Documents Department
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Laboratory Development of the Thorex Process

Description: Changes made in the Thorex process flowsheet were a decrease in the extraction column acidity to decrease thorium losses and the addition of a second thorium solvent-extraction cycle to provide the increased decontamination required when thorium irradiated to 2000-4000 g of U233 per ton is processed. Bonded slugs could not be dissolved by the Thorex flowsheet procedure. Various laboratory scale studies on feed preparation, first-cycle variables, and radiation damage to the solvent are reported.
Date: June 12, 1956
Creator: Wischow, R. P. & Mansfield, R. G.
Partner: UNT Libraries Government Documents Department
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Chemical Separation of Isotopes Section Semiannual Progress Report for Period Ending June 30, 1955

Description: The countercurrent gas-liquid system BF3(g)—anisole·BF3(l) for the concentration of boron isotopes has been studied. The single-storage separation factor varies from 1.039 at 0°C to 1.029 at 30°C. Rate of exchange is rapid, and, with efficient contacting equipment, complete exchange may be obtained in less than 15 sec. A total separation of 1.525 has been realized in laboratory equipment. The critical-product reflux reaction is quite efficient. Only about 55 moles of BF3 remain in each million … more
Date: February 23, 1956
Creator: Clewett, G. H. & Drury, J. S.
Partner: UNT Libraries Government Documents Department
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Aircraft Nuclear Propulsion Project Quarterly Progress Report for Period Ending December 10, 1955

Description: This quarterly progress report of the Aircraft Nuclear Propulsion Project at ORNL records the technical progress of the research on circulating-fuel reactors and other ANP research at the Laboratory under its Contract W-7405-eng-26. The report is divided into three major parts: I. Reactor Theory, Component Development, and Construction, II. Materials Research, and III. Shielding Research. The ANP Project is comprised of about 530 technical and scientific personnel engaged in many phases of rese… more
Date: March 12, 1956
Creator: Jordan, W. H.; Cremer, S. J.; Miller, A. J. & Savelainen, A. W.
Partner: UNT Libraries Government Documents Department
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ORNL Mortal Recovery Plant: Processing of ORNL Graphite Reactor Fuel Elements During the Period July and August, 1955

Description: From July 7 to August 31, 1955, 20 tons of uranium and 1,200 g of plutonium were recovered in 47 days of plant operation at an average rate of 833 lb/day of uranium and at a cost of $2.60/lb of uranium. Uranium and plutonium recoveries were, respectively, 99.9 and 95.5 per cent.
Date: November 11, 1955
Creator: Brooksbank, R. E.; Chandler, J. M. & Hylton, C. D.
Partner: UNT Libraries Government Documents Department
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Preliminary Results of APPR Critical Experiments, Part I.

Description: This memorandum is the first in a series reporting progress in the program of critical experiments in the ORNLArmy Package Power Reactor Project. The critical assembly, designated as CA-25, is analogous to the APPR design core and consists of 45 fuel boxes, in a 7 x 7 array with the corners removed, contaIned in a large water tank. Two sides of each box are slotted for the insertion and positioning of any desired loading of eighteen plates of fuel, structural material, and poison. The array is … more
Date: November 25, 1955
Creator: Williams, D. V. P.
Partner: UNT Libraries Government Documents Department
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Development of a Cubic Oxide Protective Film on Zirconium

Description: Observations of the effects of neutron damage to zirconium oxides led to the conclusion that the cubic form of ZrO2 is more stable to such damage than the monoclinic form. It has been reported that zirconium corrodes more rapidly in certain liquids when exposure is made under radiation (neutrons and fission products). It is well known that on heating monoclinic ZrO2 a transformation, monoclinic to tetragonal (very similar to cubic), occurs at about 1500°C. The transformation involves sufficient… more
Date: February 21, 1956
Creator: Johnson, J. R.
Partner: UNT Libraries Government Documents Department
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Bibliography of ORNL-BSF Reports Pertinent to Swimming Pool Type Reactor Design (Revised)

Description: Much of the shielding work carried out with the Bulk Shielding Reactor (BSR) has yielded data of particular interest for the design of swimming pool type reactors, However, it is often difficult for a reactor designer to locate such data since it may be recorded in a report primarily concerned with shielding problems. Therefore, this memorandum presents a bibliography of reports from the Bulk Shielding Facility arranged according to the application of data to the various aspects of reactor desi… more
Date: April 13, 1956
Creator: Maienschein, F. C. & Johnson, E. B.
Partner: UNT Libraries Government Documents Department
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Fission Product Activities in Irradiated Natural Uranium, Enriched Uranium, and Thorium

Description: Calculated data and graphs describing the effects of batch thermal-neutron irradiations on the buildup of fission products in natural uranium, enriched uranium, and thorium are presented together with empirical equations and plots correlating total fission product activities and/or decontamination factors. Fluxes of 1012-1015 are considered.
Date: March 28, 1956
Creator: Arnold, E. D.
Partner: UNT Libraries Government Documents Department
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HRP Radiation Corrosion Studies

Description: A fifth in-pile loop experiment, L-4-8, was completed. The loop operated in-pile for a total of 1637 hr, during which time the LITR energy output was 4377 Mwhr. The average fission power in the loop based o cesium analyses was 622 w when the LITR was at full power (3 Mw). Based on oxygen data, the generalized corrosion rate for the first 300 hr was 4.0 mpy; the rate for the remaining 1357 hr was 0.7 mpy. The nickel data gave parallel results. The corrosion of the type 347 stainless steel, Zirca… more
Date: August 21, 1956
Creator: Baker, J. E.; Bradley, N. C.; Jenks, G. H.; Olsen, A. R.; Savage, H. C. & Walter, F. J.
Partner: UNT Libraries Government Documents Department
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Chemistry Division Semiannual Progress Report for Period Ending December 20, 1955

Description: Semiannual Progress report of the Oak Ridge National Laboratory Chemistry Division providing updates on various projects, experiments, and other work in inorganic and physical chemistry, nuclear chemistry, organic chemistry, chemical physics, chemistry of separation processes, radiation chemistry, and reactor chemistry.
Date: April 13, 1956
Creator: Taylor, E. H. & Bredig, M. A.
Partner: UNT Libraries Government Documents Department
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Biology Division Semiannual Progress Report for Period Ending February 15, 1956

Description: Progress report of the Oak Ridge National Laboratory Biology Division providing updates on various projects, experiments, and other work. This report includes a summary of scholarly output from the division and departmental activities in cytology and genetics, mammalian genetics and development, microbial protection and recovery, mammalian recovery, pathology and physiology, general physiology, biochemistry, enzymology and photosynthesis, microbiology, plant biochemistry, and biophysics.
Date: April 20, 1956
Creator: Hollaender, Alexander & Carson, Stanley F.
Partner: UNT Libraries Government Documents Department
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High-Thermal-Conductivity Fin Material for Radiators

Description: This report is the result of a study to develop heat-resistant fin materials possessing a high thermal conductivity for air radiators. Since an economical and commercially feasible product was desired, the investigation was restricted primarily to a study of electroplated copper, clad copper, and copper alloys. Sheet material 0.008 to 0.010 in. thick was evaluated for fabricability and for metallurgical stability and thermal conductivity at 1500°F. From the results of the rests it was concluded… more
Date: January 24, 1957
Creator: Inouye, H.
Partner: UNT Libraries Government Documents Department
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Analytical Chemistry Division Semiannual Progress Report for Period Ending April 20, 1954

Description: Progress report of the Oak Ridge National Laboratory Analytical Chemistry Division providing updates on various projects, experiments, and other work in ionic analyses, analytical instrumentation, radiochemical analyses, activation analyses, spectrochemical analyses, inorganic preparations, optical and electron microscopy.
Date: July 5, 1956
Creator: Kelley, M. T.; Susano, C. D. & Raaen, H. P.
Partner: UNT Libraries Government Documents Department
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Metallurgy Division Semiannual Progress Report for Period Ending October 10, 1955

Description: Progress report of the Oak Ridge National Laboratory Metallurgy Division providing updates on various projects, experiments, and other work. This report includes a summary of nondestructive testing, physical chemistry of corrosion, fundamental physico-metallurgical research, HRP metallurgy, process metallurgy, metallurgical materials and processing, metallography, and ceramics research.
Date: June 14, 1954
Creator: Manly, W. D.
Partner: UNT Libraries Government Documents Department
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HRT Reactor Hazards

Description: Several potential hazards that have been recognized and anticipated in the design and fabrication of the pressure vessel in the Homogeneous Reactor Test are discussed. These hazards results from the high operating pressure and temperature of the reactor, the exposure of the reactor vessel material to potential embrittlement and other affects of fast-neutron irradiation, and the need for containment of corrosive flowing liquids. The steps taken in recognition of these hazards are also discussed.… more
Date: August 3, 1956
Creator: Miller, E. C.
Partner: UNT Libraries Government Documents Department
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Aircraft Nuclear Propulsion Project Quarterly Progress Report for Period Ending June 10, 1956 [Declassified Version]

Description: Progress report of the Oak Ridge National Laboratory Aircraft Nuclear Propulsion Project providing updates on various projects, experiments, and other work. This report includes summaries of project activities in: aircraft reactor test design, ART physics, ART instruments and controls, component development and testing, procurement and construction, ART, ETU, and in-pile loop operations, phase equilibrium studies, chemical reactions in molten salts, physical properties of molten materials, prod… more
Date: September 4, 1956
Creator: Jordan, W. H.; Cramer, S. J.; Miller, A. J. & Savelainen, A. W.
Partner: UNT Libraries Government Documents Department
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Basic Gamma-Ray Data for ART Heat Deposition Calculations

Description: In order that fairly accurate thermal stress calculations can be made on the ART, it is necessary to have a reasonable picture of the temperature distribution in the reactor. To get the temperature distributions, and to determine cooling requirements in various parts of the reactor, one must know the heat deposition rates due to alpha particles, beta rays, gamma rays, and neutrons in all parts of the reactor. The present report contains only the basic physical data necessary to determine the he… more
Date: October 3, 1956
Creator: Bertini, H. W.; Copenhaver, C. M.; Perry, A. M. & Stevenson, R. B.
Partner: UNT Libraries Government Documents Department
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A Physical Property Summary for Fluoride Mixtures

Description: This report presents a summary of certain physical properties that have been determined experimentally on the fluoride mixture that have been formulated at ORNL (Rers. 1, 2). These properties include the density, enthalpy, heat capacity, heat of fusion, thermal conductivity, viscosity, Prandtl number, electrical conductivity and surface tension. In addition to the experimental data, values have been predicted for the heat capacity and density of the other mixtures from the correlations of these… more
Date: September 5, 1956
Creator: Cohen, S. I.; Povers, W. D. & Greene, N. D.
Partner: UNT Libraries Government Documents Department
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Stable Isotope Research and Production Division Semiannual Progress Report

Description: The Spectroscopy Research Laboratory is concerned with research and development in the fields of nuclear magnetic resonance, microwaves, infrared and optical spectroscopy, spectrochemistry, and x rays. Research is directed toward fruitful methods of isotope analysis; new element and compound analytical methods having application to immediate Laboratory or long-range commission needs; and fundamental research on isotopes, elements, and compounds. The work is reported on a project basis to give a… more
Date: February 18, 1955
Creator: Keim, C. P.
Partner: UNT Libraries Government Documents Department
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