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Feasibility of a Liquid Phase Chemonuclear Ozone Process

Description: At the Chemonuclear Workshop held at Brookhaven National laboratory in November 1962 it was pointed out that the production of ozone from oxygen by a liquid phase fission fragment chemonuclear process appears to have reasonable economic potential. The maximum theoretical reaction yield for the formation of ozone from oxygen is a "G" value of 68 molecules for 100 ev based on heat of reaction data. The authors felt a "G" value of 15 to be reasonable for this study. the reactor system chosen has l… more
Date: November 19, 1963
Creator: Cagnetta, J. P.; Goellner, D. & Steinberg, M.
Partner: UNT Libraries Government Documents Department
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Fluxes and Reaction Rates in the Presence of Interferring Resonances

Description: The effects of competition between resonances of different isotopes were investigated. Flux and reaction rate calculations on a Pu/sup 239/-- U/sup 238/ system revealed that U/sup 238/ exhibits both self-shielding and interference effects, the latter becoming noticeable at enrichment of a few per cent. Gold activation was also found to be depressed by the presence of U, but was insensitive at low enrichment values, Investigation of the Pu/sup 239/ resonance integral showed an asymmetric effect … more
Date: November 1963
Creator: Kelber, Charles N.
Partner: UNT Libraries Government Documents Department
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Effect of Eddy Diffusion on Temperatures in a Fixed Bed, Particulate-Fueled Nuclear Reactor

Description: Abstract: To assess diffusion's importance, the temperature distribution in a cylindrical reactor is derived for a coolant with uniform properties and velocity, taking into account both radial and axial diffusion, for a cosine-J0 power distribution. The fractional temperature rise of the coolant is found to be [chemical formula] where E(z) = [sin(z) + sin(Z)]/2 sin(Z), z= π x/2′, x is the axial distance from the core center, -H and ′ are the core half-height and extrapolated half-height, -H≤x≤… more
Date: November 1963
Creator: Barker, James J. & Benenati, Robert F.
Partner: UNT Libraries Government Documents Department
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Behavior of Irradiated Metallic Fuel Elements Exposed to Nuclear Excursion in TREAT

Description: In fast reactor safety studies, it is imperative to know the effects of temperature excursions on the fuel elements. Previous controlled out-of-pile experiments on the behavior of uranium fuel elements under meltdown or near-meltdown conditions have been performed using direct electrical resistance heating or furnace heating. As a step toward obtaining more complete information on reactivity effects accompanying fuel meltdown, the behavior of irradiated EBR II and Fermi A samples under transien… more
Date: November 1963
Creator: Monaweck, J. H.; Dickerman, Charles Edward, 1932- & Sowa, E. S.
Partner: UNT Libraries Government Documents Department
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Effect of Radiation on Mechanical Properties of CVTR Pressure Tube Material

Description: An essential part of establishing the acceptability of warm extruded Zircaloy-4 for the CVTR pressure tube application was the determination of irradiation effects on mechanical properties of the alloy. Representative specimens were irradiated in low temperature process water in the WTR for simulated two, three and five year exposure. The effects of this irradiation were then evaluated in terms of changes in tensile, impact and creep properties. The experiment results concluded that the irra… more
Date: November 1963
Creator: Smalley, W. R.
Partner: UNT Libraries Government Documents Department
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The Determination of k∞ From Measurements on a Small Test Sample in a Critical Assembly

Description: Abstract. The determination of the infinite multiplication factor, k∞ , from measurement son a small test sample was investigated by both theoretical and experimental techniques. Theoretical relations were developed to calculate the error in the measurement due to a mismatch between the flux ratios in the critical assembly and those of the test sample. Experiments were carried out at the Hanford Laboratory of the General Electric Company with the PCTR, to obtain values of the multiplication f… more
Date: November 1963
Creator: Lanning, David Dayton
Partner: UNT Libraries Government Documents Department
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Pressure Pulses in Rapid Transient Boiling

Description: Investigation of whether the multi-thousand psi pressure pulses that occurred in the BORAX-I and SPERT-I destructive power excursion could have been generated by thermal mechanisms in the geometries of unmolten reactor cores. These pressure pulses were "at least as high as 6,000 psi, and probably higher than 10,000 psi " in BORAX I, and "between 3,000 and 4,000 lb/in" in SPERT I. An experimental investigation was undertaken of pressure pulse generation by purely thermal means.
Date: July 31, 1963
Creator: Wright, R. W.
Partner: UNT Libraries Government Documents Department
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Sodium Separation From Biological Material

Description: This study is part of a research into trace element physiology of fresh water snails. As an average, biological materials contain [approximately] o.0% (fresh weight) NaCl ; this means [approximately] 3540 mg Na/1 (in snails, 0.4% NaCl [approximately] ms/1). Under these conditions, the application of neutron activation plus gamma spectrum analysis for the study of most trace elements as a routine method, is difficult. We will narrow down the scope some more and consider only the interference be… more
Date: November 1963
Creator: Spronk, N.
Partner: UNT Libraries Government Documents Department
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Water Spectra and Energy Exchange Kernels

Description: Many measurement of neutron spectra have been made in water assemblies. In these system a large part of the spectrum is given by an essentially Maxwellian distribution at the moderator temperature which is insensitive to the scattering model. Hence, the test of the energy exchange scattering kernel is in the difference of the spectrum and the fundamental or Maxwellian component. The figure shows the spectrum for the Nelkin model. Once the fundamental has been subtracted neither theoretical mode… more
Date: July 11, 1963
Creator: Daitch, Paul B. (Paul Bernard), 1925- & Ohanian, M. J.
Partner: UNT Libraries Government Documents Department
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Asymptotic Neutron Spectra in Multiplying Media

Description: Asymptotic low energy neutron spectra have been measured for two multiplying systems. The reentrant hold spectrum (scalar flux) and the surface leakage spectrum were obtained for both assemblies using the pulsed-source chopper technique at the RPI linear accelerator.
Date: November 1963
Creator: Slovacek, R. E.; Fullwood, R. R.; Gaerttner, Erwin Rudolf, 1911- & Bach, D. R.
Partner: UNT Libraries Government Documents Department
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Diffusion Parameters of Water for Various Scattering Kernels

Description: Abstract. Some diffusion parameters of water are computed with various thermal-neutron scattering laws. It is found that the diffusion cooling coefficient, in particular, is reasonably sensitive to the scattering law, but that the diffusion cooling coefficients predicted by the Radkowsky and Nelkin kernels are in fortuitious agreement. The coefficients computed for the Nelkin kernel, when treated in a manner consistent with the way in which experimental data are treated, are in reasonable agree… more
Date: August 16, 1963
Creator: Calame, Gerald P.
Partner: UNT Libraries Government Documents Department
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An Electrochemical pH-STAT

Description: An apparatus has been developed which controls automatically the acidity of unbuffered solutions in the region from pH 4 to 10. A potentiostat is used to control the potential of an inert electrode on which the hydrogen gas-hydrogen ion reaction occurs in a solution saturated with hydrogen gas. The inert electrode acts as both a sensing element and a regulating electrode for the control of acidity. Current from the potentiostat passes through the inert electrode and an auxiliary polarizing elec… more
Date: October 1963
Creator: Posey, F. A. (Franz Adrian), 1930-; Morozumi, T. & Kelly, E. J.
Partner: UNT Libraries Government Documents Department
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The Scattering of Lattice Vibrations by Vacancy Type Defects

Description: Abstract. A brief review of the development of the subject of lattice defects in solids is given. The relation of this problem to field theory methodology is discussed; the defect is regarded as a particle imbedded in the phonon field. One may then discuss scattering states in the field, or “dressed” states of the particle. Specific application is then made to a defect in a simple cubic crystal including interactions between the defect site and its six nearest neighbors. Scattering solutions an… more
Date: August 1963
Creator: Krumhansi, James A.
Partner: UNT Libraries Government Documents Department
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Sorption Measurements in Ultrahigh Vacuum at Constant Pressure

Description: Introduction. Sorption of gases by surfaces is the primary step in many heterogeneous processes. Because sorption processes are in general pressure-dependent, and very fast at normal pressures, low pressure system are mandatory. In gas-metal interaction studies the flash filament technique with ribbons and filaments and Wagener's technique with evaporated films allow observations at the requisite low pressures. However, these method have two major drawbacks: (1) Since the pressure changes dur… more
Date: October 1963
Creator: Gibson, Richard.; Bergsnov-Hansen, B.; Endow, Noboru. & Pasternak, R. A.
Partner: UNT Libraries Government Documents Department
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Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol

Description: Abstract. By means of the pulse radiolysis technique a short-lived transient species has been observed in irradiated de-aerated ethanol and methanol, exhibiting an optical absorption throughout the visible and near infra-red. This transient is suggested to be the solvated electron on the basis of the nature of the spectrum, the reactivity with hydrogen ion and with various organic electron acceptors, and the formation of mononegative ions of some of these acceptors. The absolute rate constants … more
Date: June 10, 1963
Creator: Taub, Irwin A.; Sauer, Myran, C., Jr. & Dorfman, Leon M.
Partner: UNT Libraries Government Documents Department
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Reactions of the Hydrated Electron

Description: Abstract. The rate constants for the reaction of the hydrated electron eaq with a number of solutes and with radicals formed in water radiolysis are reported. Hydrated electrons were formed in the electron pulse irradiated solutions at concentrations in the range from 1 to 10 pM. Their reaction was followed by the decay of the optical absorption of eaq at 5780 A. Generally a 04 psec pulse of 15 MeV electrons was used. In the absence of eaq scavengers, second-order kinetics prevailed owing to th… more
Date: June 17, 1963
Creator: Gordon, S.; Hart, E. J.; Matheson, Max S. & Rabani, J.
Partner: UNT Libraries Government Documents Department
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Gas-Phase Radiolysis of Propane

Description: Abstract. the direct and inert-gas radiolysis, as well as the vacuum ultra-violet photolysis of CD3CH2CD3, CH3CD2CH3 and C3H2+C3D3 mixtures have been investigated in the presence of radical scavengers. The major conclusions are : (a) at atmospheric pressures, neutral propane decomposition contributes to the observed products although to a lesser extent than parent ion decompositions ; (b) a variation in pressure has a pronounced effect on the fragmentation of the parent ion ; (c) the hydrogen a… more
Date: May 31, 1963
Creator: Ausloos, Pierre J.; Lias, Sharon G., 1935- & Sandoval, L. B., (Mrs.)
Partner: UNT Libraries Government Documents Department
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Effect of Fluoride Ions on the Aqueous Corrosion of Zirconium Alloys

Description: Abstract. A review has been made of the effects of fluoride ions on the corrosion behavior of zirconium alloys in high-temperature water. Corrosion was found to occur as the result of contamination of the water or the zirconium surface. A major source of fluorides is undue delay in rinsing the HF-HNO3 pickling solution during surface preparation. The oxide on corrosion-resistant material has been found to contain up to 7600 ppm fluoride from this source. The threshold concentration of fluoride … more
Date: November 1963
Creator: Berry, Warren E., 1922-
Partner: UNT Libraries Government Documents Department
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A High Speed Readout for Multi-Channel Pulse Height Analyzers

Description: From American Nuclear Society Meeting, New York, Nov. 1963. In computer-coupled automated activation analysis such as in the Mark II system, conventional methods of data readout impose a serious restriction on the minimum handling time per sample. A data coupler for operating between the data accumulation system and the computer tape unit was developed which contributes nothing to the handling time per sample, does not distort the data, and prepares the data for direct computer entry. In additi… more
Date: November 1963
Creator: Wilkins, W. W.; Fite, L. E. & Wainerdi, Richard E., 1931-
Partner: UNT Libraries Government Documents Department
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Current-Carrying Capacity and Transition State of Superconducting Solenoids

Description: Montgomery and Chandrasekhar and Hulm suggested models for predicting Im and Hm of high-field superconducting solenoids. Montgomery's model for predicting the degradation effect of superconducting solenoids leads to a unique coil quenching characteristics if geometrically similar solenoids are considered. Experiments do not verify these predicted results. Chandrasekhar and Hulm's model leads to one unique coil quenching characteristic for all solenoids with identical wire type and turn distan… more
Date: September 3, 1963
Creator: Gauster, W. F. & Coffey, D. L.
Partner: UNT Libraries Government Documents Department
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Reactivity Worth of Transverse Gaps

Description: Technical report discussing a series a experiments on the reactivity worth of gaps has been performed in the KAPL Solid Homogeneous Assembly (SHA). One objective of the program is to provide data against which calculated models can be checked. An immediate goal is to develop a method by which large void regions can be adequately treated within the framework of diffusion theory. This would enable the nuclear engineer to perform standard design calculations on systems containing such voids. Ano… more
Date: November 1963
Creator: Weinstein, S. & Feiner, Frank
Partner: UNT Libraries Government Documents Department
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Recent Developments in the Physics and Safety of Large Fast Power Reactors

Description: Technical report discussing three principal areas: (1) some recent cross section measurements and their effect on fast reactor calculations; (2) the question of Doppler and sodium void reactivity effects in large fast power reactors and the conflicts inherent in simultaneous optimization of performance, breeding, and safety characteristics; (3) the matter of hybrid fuel cycles.
Date: November 1963
Creator: Okrent, David
Partner: UNT Libraries Government Documents Department
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Beta Radiation Processing at Rigorous Conditions

Description: Introduction: The literature reflects ever expansive studies of radiation chemistry over the past twenty years However, in the application of radiation processing to chemical reactions, in general and excepting a few isolated cases, the yield of useful products have been so low as to preclude practical utilization. Thus, for many reactions,radiation alone at ambient conditions is not a sufficient agent for economical production. Hence, we are led to the investigation of radiation effects on … more
Date: November 15, 1963
Creator: Yavorsky, P. M. & Gorin, E.
Partner: UNT Libraries Government Documents Department
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Development and Evaluation of Large Volume Scintillation Detectors and Their Application to Radioisotope Process Control

Description: Preliminary phases of this investigation that have been completed include basic studies to determine optimum detector engineering characteristics and static tests of a number of designs. A pilot system for dynamic testing of the detectors in simulated process control applications is presently in operation.
Date: November 1963
Creator: Perry, J. Kent
Partner: UNT Libraries Government Documents Department
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