The single electron chemistry of coals. [Quarterly] report, January 1--March 31, 1993
Description:
Following the position of the nitrile band and using the assumption that there is a linear relationship for between the extent of charge transfer and frequency, a 69% charge transfer was obtained and successfully replicates Flowers` results. If a Diels-Alder reaction occurred, we would expect the position of nitrile group to have shifted down field to the 2260-2240 cm{sup {minus}1} range for a saturated alkyl nitrile. There is no evidence for this type of reaction under these conditions since w…
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Date:
September 1, 1993
Creator:
Larsen, John W. & Rothenberg, S. E.
Partner:
UNT Libraries Government Documents Department