Quadrupole mass-filter sensitivities of H/sub 2/, HD, D/sub 2/, and T/sub 2/, and the kinetics of. beta. -particle induced exchange between H/sub 2/, D/sub 2/, and T/sub 2/ at 25. 4/sup 0/C
Description:
We have constructed a quadrupole-mass filter system to measure the equilibrium constants and rates of reaction of the ..beta..-particle-induced exchanges between H/sub 2/, D/sub 2/, and T/sub 2/ at cryogenic temperatures. Even with careful calibration experiments at 25.4/sup 0/C, we could not completely remove the mass discrimination inherent in our method. We estimate the accuracy of our mixture analyses to be +-2.2% in the D/sub 2/-DT-T/sub 2/ system, and +-9% in the H/sub 2/-HT-T/sub 2/ syst…
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Date:
January 11, 1978
Creator:
Pyper, J. W.; Kelly, E. M.; Magistad, J. G.; Tsugawa, R. T.; Roberts, P. E. & Souers, P. C.
Partner:
UNT Libraries Government Documents Department