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The Kinetics of the Complexing of Ferric Ion by Thiocyanate and Chloride Ions

Description: An apparatus for rapidly mixing two solutions and recording the light absorption, which was developed by Connick and Below, has been modified. The mixing characteristics were studied and models were developed in an attempt to umder stand the observed mixing phenomena. The apparatus was applied to a study of the kinetics of the reactions Fe/sup +++/ + SCN/sup -/ = FeSCN/sup ++/ and Fe/ sup +++/ Cl/sup -/ = FeCl/sup ++/ in aqueous solution, with both reactions having the forward rate law STAd(FeX… more
Date: December 1, 1957
Creator: Coppel, Claude Peter
Partner: UNT Libraries Government Documents Department
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Studies Relating to the Structure of Aluminum Hydride

Description: The object of the work was to determine the molecular structure of AlH/ sub 3/, using the techniques of nuclear spin resonance.'' Attempts to prepare ether-free AlH/sub 3/ that were unsuccessful are described. Also it was not possible to observe the deuterium signal in AlH/sub 3/. It was possible, by the use of the proton signal of the ether in AlH/sub 3/, to obtain the nuclear spin resonance absorption curve for AlH/sub 3/ by subtracting out the contributions of the ether protons to the resona… more
Date: December 16, 1957
Creator: Nickerson, R. F.
Partner: UNT Libraries Government Documents Department
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