19-electron intermediates in the Ligand Substitution of CpW(CO)3with a Lewis Base
Description:
Odd electron species are important intermediates in organometallic chemistry, participating in a variety of catalytic and electron-transfer reactions which produce stable even-electron products. While electron deficient 17-electron (17e) radicals have been well characterized, the possible existence of short-lived 19-electron (19e) radicals has been a subject of continuing investigation. 19e radicals have been postulated as intermediates in the photochemical ligand substitution and disproportion…
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Date:
December 14, 2005
Creator:
Cahoon, James F.; Kling, Matthias F.; Sawyer, Karma R.; Frei,Heinz & Harris, Charles B.
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