Solution Studies of ⁶Li Enriched Organolithium Compounds Using New NMR Techniques
Description:
With the values of 6Li T1 measured and the literature values of J(13C-6Li) for these compounds, three new 13C NMR techniques are developed for the analysis of organolithium compounds. Modifications to the spectrometer are discussed, as well as calibrations of the 6Li decoupler channel needed to set up these new experiments. The theoretical development of each technique is presented, as well as data from their verification, using organolithium compounds of known structure. Once qualified, the ne…
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Date:
May 1990
Creator:
Ellington, Donald H. (Donald Howard)